Estimated Historical and Current Nitrogen Balances for Illinois

The Midwest has large riverine exports of nitrogen (N), with the largest flux per unit area to the Mississippi River system coming from Iowa and Illinois. We used historic and current data to estimate N inputs, outputs, and transformations for Illinois where human activity (principally agriculture and associated landscape drainage) have had a dominant impact. Presently, ~800,000 Mg of N is added each year as fertilizer and another 420,000 Mg is biologically fixed, primarily by soybean (Glycine max L. Merr.). These annual inputs are greater than exports in grain, which results in surplus N throughout the landscape. Rivers within the state export approximately 50% of this surplus N, mostly as nitrate, and the remainder appears to be denitrified or temporarily incorporated into the soil organic matter pool. The magnitude of N losses for 1880, 1910, 1950, and 1990 are compared. Initial cultivation of the prairies released large quantities of N (~500,000 Mg N year�1), and resulted in riverine N transport during the late 19th century that appears to have been on the same order of magnitude as contemporary N losses. Riverine flux was estimated to have been at a minimum in about 1950, due to diminished net mineralization and low fertilizer inputs. Residual fertilizer N from corn (Zea mays L.), biological N fixed by soybean, short-circuiting of soil water through artificial drainage, and decreased cropping-system diversity appear to be the primary sources for current N export.

Rate of recycling of sulfur from urine, feces and litter applied to the soil surface

The recycling of S from plant litter, dung and urine is an important process for supplying S for pastures. A pot experiment was conducted where 35S-labelled litter (25% white clover/38% ryegrass/21% weed) and S-35-labelled urine and faeces collected from sheep fed the same herbage as was used as litter was surface applied to pots and the fate of the applied S was followed for 100 days with ryegrass as the test plant. In camp soil, 45% of the S applied in urine was taken up by ryegrass plants within 12 days of application. In non-camp soil, the uptake of urine-S was about 20% over the same period. Cumulative uptake of 35S from urine in camp soil was subsequently restricted, with a maximum of 60% eventually measured in plants after 100 days. Mean rates of release of S (0-37 days) from litter and faeces was respectively 16.2 and 4.5 mg g-1 day-1. The calculated half-times from S in the two materials were respectively 43 and 154 days under controlled environmental conditions with adequate moisture. Litter S followed organic matter (OM) decomposition, but faecal S release was initially more rapid than faecal OM decomposition. There was little S release from faeces after day 25. Rather, S was immobilized in faeces during the 25-100 day period. The decomposition of litter and faeces was divided into an initial rapid process during which soluble S and more labile S was released, followed by a slower process involving the release of S from tissues more resistant to mineralization. The uptake of 35S from labelled materials was initially more rapid than would be expected for total S released from the added litter and faeces and the 35Suptake effect was short-lived relative to the continued effect of added material on total S uptake. The preferential uptake of 35S from the surface-applied material appears to be due to limited root development at the early stages of the experiment. Movement of 35S into the soil organic matter pool was very rapid; 58.4% of urine S was in the soil organic matter fraction in the non-camp soil by day 6. The amount of applied S in the organic matter equilibrated at about day 75. The accumulation of applied S from the materials added was greater than that recorded in previously reported studies for inorganic sulfate (e.g. about 50%). Soil P and S status had little effect on rates of release of S. from the applied materials, however, the effect of the camp and non-camp soil on total S recycling was markedly different as a result of the different amounts of plant growth and thus S uptake in the two soils. The decomposition of litter indicated peak rates of S release at two specific times over the 100 days and indicated successional changes in micro-organism activity. With faeces, the experiment was not continued for sufficiently long to show micro-organism effects.

Components of the fertiliser nitrogen balance for wheat production on duplex soils

In this paper, we review literature on the fate of fertiliser nitrogen (N) applied to duplex soils in wheat-growing regions of southern Australia, and discuss the contribution of specific N transformations to N loss. Duplex soils are characterised by the presence of soil material, within the rooting depth of crops, that possess hydraulic conductivities that are lower than those of overlying material. Denitrification and the transport of nitrate below rooting depth of crops are thought to be the chief causes of loss of fertiliser N and to contribute to poor grain yields. Ammonia volatilisation could contribute also to N loss. The fate of fertiliser N commonly applied to wheat in southern Australia has largely been evaluated using budgeting procedures using l5N, a stable isotope of N. Results from studies in south-eastem Australia, using red-brown earths, indicate that between 10 and 40% of applied 15N can be lost irrespective of time of application to wheat. Denitrification is believed to be the chief cause of loss of l5N. Similar studies on yellow duplex soils in Western Australia have shown fertiliser N loss to range from 70% to no loss of the l5N applied. The exact cause of N loss in Western Australian studies is unclear. There was circumstantial evidence for ammonia loss from surface-applied urea, and evidence of leaching of nitrates from this and other ammoniumbased fertilisers. The role of denitrification has not been clarified in Western Australian studies. In the majority of studies, recovery of 15N in aboveground biomass exceeded 40% of that applied. In addition, between 17 and 48% of applied 15N, of which 10-15% may be in root material, has been recovered in the soil organic matter pool. The predominance of the denitrification process in south-eastern Australian soils, and the inability to improve the efficiency of utilisation of 15N by delaying the time of application to wheat underscores the importance of controlling the nitrification process using inhibitors. Management options for Western Australian soils are less clear. Some agronomic experiments have demonstrated the advantage of delaying the application of fertiliser N to wheat to improve the efficiency of its utilisation. There is also evidence which suggests that N should be applied early in the growth cycle to promote tiller development and thereby increase the potential for grain yield.