Hydrodynamics of an airlift reactor for aeration in molten sulfur

An industrial-scale internal loop airlift reactor is used to remove volatile gas from high-viscosity molten sulfur. The effects of the superficial gas velocity and reactor height on the hydrodynamic characteristics were studied. The gas holdup, average bubble diameter, and liquid circulation velocity in the reactor under different conditions were analyzed using computational fluid dynamics simulation. The superficial gas velocity was varied from 0.0056 m/s to 0.05 m/s at a constant reactor height of 15 m. The total reactor height was varied from 5 m to 25 m at a superficial gas velocity of 0.0389 m/s.Based on the correlation between the gas holdup and liquid circulation velocity proposed by Chisti (1988), an optimized correlation between the gas holdup and liquid circulation velocity was developed by considering the influence of the bubble diameter. The results obtained using the proposed correlation were compared with those obtained using the Chisti correlation and simulation.

Numerical study of the hydrodynamics and mass transfer in the external loop airlift reactor

The objective of this study was to investigate the hydrodynamics and the gas-liquid mass transfer coefficient of an external-loop airlift reactor (ELAR). The ELAR was operated in three cases: different inlet velocities of fluids, different alcohols solutions (water, 0.5% methanol, 0.5% ethanol, 0.5% propanol and 0.5% butanol) and different concentration of methanol in solutions (0%, 0.5%, 1%, 2% and 5%). The influence of superficial gas velocity and various diluted alcohol solutions on hydrodynamics and gas-liquid mass transfer coefficient of the ELAR was studied. Experimentally, the gas hold-up, liquid velocities and volumetric mass transfer coefficient values in the riser and the downcomer were obtained from the literature source. A computational fluid dynamics (CFD) model was developed, based on two-phase flow, investigating different liquids regarding surface tension, assuming the ideal gas flow, applying the finite volume method and Eulerian-Eulerian model. The volumetric mass transfer coefficient was determined using CFD model, as well as artificial neural network model. The effects of liquid parameters and gas velocity on the characteristics of the gas-liquid mass transfer were simulated. These models were compared with appropriate experimental results. CFD model successfully succeed to simulate the influence of different alcohols regarding the number of C-atoms on hydrodynamics and mass transfer.