The influence of the nature of the water-soluble polymer on the dimensional characteristics, morphology and chemical composition of cobalt-containing particles obtained in polymer films has been investigated. In the presence of polystyrene sulfonic acid and polyacrylic acid, polydisperse particles with a size of 20-50 nm are formed, forming aggregates of various structures. In the poly-N-vinylpyrrolidone film, the resulting particles are uniformly distributed over the film surface, do not form aggregates and have an average size of 30-40 nm. The chemical composition of the resulting particles was determined by X-ray microanalysis.