Mercury Speciation in Natural and Mining-Related Systems

Mercury speciation and the composition of mercury phases in natural and mining-related environments is studied by the thermal release analysis combined with electrothermal atomic absorption spectroscopy (TA-ET-AAS), as well as scanning electron microscopy with energy-dispersive X-ray microanalysis (SEM-EDS). The analyses are applied to laboratory-made samples bearing mercury selenide and to field samples from sites known for relatively high natural or industrially induced Hg background. They are, namely, material from the dispersion train of the Ursk sulfide tailings (Ursk Village, Kemerovo region) and debris precipitated from snow sampled in the Kurai mercury zone (Aktash Village, Gorny Altai). The TA-ET-AAS method works well in discrimination and identification of Hg sulfide and Hg selenide provided that the samples contain sufficient amounts of both compounds, but the sum HgS + HgSe can be determined at any contents of the two compounds. The presence of both mercury sulfide and mercury selenide in the samples has been confirmed by SEM-EDS microanalysis. The temperature ranges for the mercury species (Hg2+; HgS+HgSe mixture; mercury bound with organic matter (Hg-OM), including CH3Hg+) are identical in the laboratory and field samples. Therefore, the suggested approach can ensure fast and reliable detection of Hg phases in rocks exposed to supergene alteration

Natural organic matter from the dispersion train of gold sulfide tailings: group composition and fractionation of elements: case study of Ursk tailings, Kemerovo region, Siberia

We study the contents of elements and group composition in natural organic matter (NOM) that interacts with acid mine drainage (АMD) and high-sulfide tailings at the Ursk site (Southwestern Siberia, Russia). AMD causes biomass changes in NOM, related changes in the composition of fractions, and hydrolysis of hydrolyzable compounds; it increases the water-soluble fraction and maintains depolymerization of humic acids to fulvic acids, but exerts no effect on substances soluble in organics (bitumen) and on poorly hydrolyzable compounds. Accumulation of inorganic elements and precipitation of minerals obscure the true fraction composition of NOM: the superposed mineral component contributes significantly to the water-soluble, humic acid, hydrolyzable, and non-hydrolyzable fractions, and may reach 26.4 % per total of all fractions. Rock-forming and potentially toxic elements partition among NOM fractions and predominate in the water-soluble fraction. The contents of Au and Ag are the highest in the fractions of humic acids and hydrolyzable compounds but are lower in the non-hydrolyzable residue. The obtained data have implications for possible migration of potentially toxic elements and noble metals and thus for remediation of polluted areas. The observed fractionation of Ag and Au in NOM helps understand the mechanisms of their distribution in organic-bearing environments, such as peatlands or coal basins.

Laboratory study of low-sulfide tailings covers with elevated water table to prevent acid mine drainage

The use of monolayer covers combined with an elevated water table (EWT) is a promising reclamation method that relies on the low gas-diffusivity of water to limit oxygen ingress into potentially acid-generating tailings. A monolayer cover is installed over the sulfidic material and the water table level is controlled to maintain the tailings close to saturation. A protocol including laboratory columns was conducted to evaluate the sensitivity of the technique to parameters including cover thickness, water table level, and the presence of an anti-evaporation layer. Two types of desulfurized tailings were evaluated: silty tailings from Westwood mine and sandy tailings from Goldex mine. Data used to evaluate the covers performances included volumetric water content, suction, oxygen concentrations, and oxygen consumption. Results showed that both cover materials could be used to maintain the reactive tailings at a degree of saturation ≥90% when the EWT level was maintained at a maximum distance of 1 m below the tailings surface. The finer Westwood material showed a better capacity for limiting oxygen migration through the cover, with a maximum flux of 5.7 mol·m−2·year−1 measured near the cover base.