The kinetics and equilibria involved in the aldol condensation of acetophenone, acting as carbon acid, and acetone have been studied in aqueous alkaline solution. The reactions are all first order in hydroxide, with rate and equilibrium constants (defined for enone as initial compound) of: k12 = 3.3 × 10−4 M−1 s−1, k21 = 3.2 × 10−5 M−1 s−1K12 = 10.2, k23 = 8.0 × 10−2 M−1 s−1, k32 = 3.3 × 10−4 M−2 s−1, K32 = 4.1 × 10−3 M−1. The series methylbutenal, mesityl oxide, and 3-methyl-1-phenyl-2-buten-1-one can now be compared with regard to regularities and deviations from regularity. The related series cinnamaldehyde, benzalacetone, and chalcone also provides insights into the behaviour of this system. Key words: aldol, dehydration, equilibrium, acetophenone, acetone.