The title compound, (Hdipya)(H3pyr), where Hdipya is protonated
2,2?-dipyridilamine and H3pyr is monoanion of pyromellytic acid (H4pyr), was
obtained from the reaction mixture containing Zn(II) ions, dipya, Na4pyr
(the molar ratio 2 : 2 : 1) and HNO3. The products (micro- and
single-crystalline) were characterized by X-ray structure determination,
FT-IR spectroscopy and TG/DSC analysis. The most striking structural feature
of (Hdipya)(H3pyr) are short inter- and extremely short intramolecular
hydrogen bonds. These bonds mutually connect cations and anions making thin
layers parallel to the crystallographic (223) plane. Also, quite unusual,
linear proton-bound polymeric {H(H2pyr)-}n anions were identified in the
structure. The results of crystal structure determination are compared with
FT-IR and TG/DSC data. The low position of nas(COO) vibration at 1660 cm-1
is in accordance with strong hydrogen bonding. This value can be used as a
measure of C=O bond order, which is calculated to be 1.81.