Ecotoxicological evaluation of construction products: inter-laboratory test with DSLT and percolation test eluates in an aquatic biotest battery

Background A European inter-laboratory test with 29 participating laboratories investigated whether a battery of four ecotoxicological tests is suitable for assessing the environmental compatibility of construction products. For this purpose, a construction product was investigated with the dynamic surface leaching test (DIN CEN/TS 16637-2) and the percolation test (DIN CEN/TS 16637-3). The eluates were produced centrally by one laboratory and were tested by the participants using the following biotests: algae test (ISO 8692), acute daphnia test (ISO 6341), luminescent bacteria test (DIN EN ISO 11348), and fish egg test (DIN EN ISO 15088). As toxicity measures, EC50 and LID values were calculated. Results Toxic effects of the eluates were detected by all four biotests. The bacteria test was by far the most sensitive, followed by the algae test and the daphnia test; the fish egg test was the least sensitive for eluates of both leaching tests. The toxicity level of the eluates was very high in the bacteria, daphnia, and algae test, with lowest ineffective dilution values of LID = 70 to LID = 13,000 and corresponding EC50 values around or even below 1 volume percent. The reproducibility (approximated by interlaboratory variability) of the biotests was good (< 53%) to very good (< 20%), regardless of the toxicity level of the eluates. The reproducibility of the algae test was up to 80%, and thus still acceptable. Conclusion It can be confirmed that the combination of leaching and ecotoxicity tests is suitable to characterize with sufficient reproducibility the environmental impact posed by the release of hazardous substances from construction products.

Impact of Sewage Sludge Leaching on Soil Constituents and Quality

Activated sludge treatment plants generate large quantities of sludge each year, thereby posing a serious environmental problem. This study aims to experimentally assess the effect of rainwater on the leaching of sludge components. In this context, a percolation test was set up, and composed of PVC cylinders into which the solid substrate was introduced. Five modalities of the solid substrate were used: a sludge modality, a soil modality and three modalities with increasing percentage of sludge (1%, 5% and 25%) in the soil. The percolation water is collected during the rainy months in bottles placed below each column. Solid substrate samples were taken before the test and after one year. The physicochemical analysis of the percolation water showed an increase in the electrical conductivity, BOD5, COD, nitrogen compounds and phosphate compounds which were proportional to the percentage of sludge. The pH of the sewage sludge leachates varies from 7.61 to 7.98. Zinc and copper were the most mobilized metals. A year following the installation of the percolation test, electrical conductivity, total phosphorus (TP) and orthophosphate (PO4) contents decreased for the solid substrates using the five modalities. Furthermore, ammonium (NH4) and nitrates (NO3) levels decreased in soil mixed with 1 to 25% of sludge due to their leaching by rainwater. Collectively, these data show that the leachates through the soil mixed with sludge are stable and loaded with NO3, a plant nutrient that can contaminate the groundwater as well as the surface waters inducing their eutrophication. Furthermore, addition of sludge to the soil improves the levels of carbon, total nitrogen, TP and PO4 in the soil and thereby soil fertility. The addition of sludge, however, is not without soil contamination with heavy metals. Such soil contamination would cause pollution of surface and ground water. Reaching certain severity, it should call for the adoption of prompt measures for the protection of environment and human health.