Development of Magnesia-Spinel Brick for Transition Zone in Cement Rotary Kilns under the Vastly Increasing use of Waste

2014 ◽  
pp. 205-209
Author(s):  
Makoto Ohno ◽  
Hitoshi Toda ◽  
Kozo Tokunaga ◽  
Yoshiki Tsuchiya ◽  
Yoshio Mizuno
Keyword(s):  
Transition Zone ◽  
Magnesia Spinel ◽  
Rotary Kilns

scholarly journals Design of Magnesia–Spinel Bricks for Improved Coating Adherence in Cement Rotary Kilns

Ceramics ◽  
2021 ◽  
Vol 4 (4) ◽  
pp. 652-666
Author(s):  
Graziella Rajão Cota Pacheco ◽  
Geraldo Eduardo Gonçalves ◽  
Vanessa de Freitas Cunha Lins
Keyword(s):  
Formation Mechanism ◽  
Firing Temperature ◽  
Essential Role ◽  
Refractory Lining ◽  
Refractory Structure ◽  
Prolonged Operation ◽  
Magnesia Spinel ◽  
Coating Formation ◽  
Rotary Kilns ◽  
Coating Formation Mechanism

It is well known that doloma bricks present better coating adherence than magnesia–spinel bricks when applied in cement rotary kilns, which is related to the different coating formation mechanism. The coating has an essential role in prolonged operation by protecting the refractory lining; thus, it is important to improve its adherence on magnesia–spinel refractories. The objective of this investigation is to study different compositions of magnesia–spinel bricks, achieved by varying additives used (calcined alumina, limestone, hematite and zirconia) and firing temperature (1500 °C and 1700 °C), to enhance the coating adherence measured by the sandwich test. The results have pointed out that the use of higher firing temperature contributes positively to physical adherence due to well-sintered refractory structure and elevated permeability, attaining coating strength superior to 2 MPa. For the chemical adherence, the addition of 2 wt.% of limestone increased the coating strength to 3 MPa, but resulted in a drop in hot properties. In this context, the most suitable approach to improve adherence of clinker coating and maintain hot properties in suitable levels is to increase the firing temperature.

scholarly journals Qualitative and Quantitative Coating Tests: A Comparison in Magnesia–Spinel Refractory Bricks

Ceramics ◽  
2020 ◽  
Vol 3 (1) ◽  
pp. 144-154 ◽  
Author(s):  
Graziella Pacheco ◽  
Geraldo Eduardo Gonçalves ◽  
Vanessa Lins
Keyword(s):  
Thermomechanical Properties ◽  
Contact Method ◽  
Test Results ◽  
Protection Mechanism ◽  
Subjective Analysis ◽  
Qualitative And Quantitative ◽  
Magnesia Spinel ◽  
Rotary Kilns ◽  
Refractory Bricks ◽  
Adherence Ability

In cement processing, which involves the production of clinker in rotary kilns, the main refractories used in the transition and burning zones are magnesia–spinel bricks. These bricks present suitable chemical and thermomechanical properties, not to mention that they can be easily landfilled. Among the main wear mechanisms of these bricks in the kiln, the infiltration of alkaline salts is noteworthy and occurs through the open pores of the refractory. In this way, the coating—a clinker layer adhered to the brick surface—appears as a protection mechanism of the lining against infiltration. Thus, the objective of this investigation is to run a qualitative coating test based on the contact method, and quantitative coating test based on the sandwich method to check the suitability of the methodologies and to evaluate the coating adherence on two different magnesia–spinel bricks. It was possible to distinguish the superior adherence ability of brick B in both coatings due to the higher porosity and the presence of nonreacted ZrO2. Despite the similarity between the test results, the quantitative sandwich-coating test is preferable because it does not depend on subjective analysis.

Theoretical modeling of the regular olivine intergrowths in the mimetic paramorphosis after ringwoodite and wadsleyite

2018 ◽  
pp. 3-12
Author(s):  
B. B. Shkursky
Keyword(s):  
Transition Zone ◽  
Theoretical Modeling ◽  
Mantle Transition Zone ◽  
Misorientation Angles

Theoretical modeling of regular olivine grains misorientations in mimetic paramorphoses after ringwoodite and wadsleyite, the formation of which during the ascension of matter from the Mantle Transition Zone is expected, has been carried out. The coordinates of the misorientation axes and the misorientation angles, characterizing 10 operations of alignment in the pair intergrowths of olivine grains, eight of which are twins, are calculated. Possible conditions for the formation of mimetic paramorphoses predicted here, and the chances of their persistence are discussed. The calculated orientations are compared with the known twinning laws of olivine.

Mathematical Model of the Effective Properties of a Fiber Reinforced Composite with a Linearly Graded Transition Zone

2010 ◽  
Vol 38 (4) ◽  
pp. 286-307
Author(s):  
Carey F. Childers
Keyword(s):  
Mathematical Model ◽  
Transition Zone ◽  
Effective Properties ◽  
Local Stress ◽  
Stress And Strain ◽  
Fiber Reinforced ◽  
Strain Fields ◽  
Shear Moduli ◽  
Fiber Reinforced Composite ◽  
Reinforced Composite

Abstract Tires are fabricated using single ply fiber reinforced composite materials, which consist of a set of aligned stiff fibers of steel material embedded in a softer matrix of rubber material. The main goal is to develop a mathematical model to determine the local stress and strain fields for this isotropic fiber and matrix separated by a linearly graded transition zone. This model will then yield expressions for the internal stress and strain fields surrounding a single fiber. The fields will be obtained when radial, axial, and shear loads are applied. The composite is then homogenized to determine its effective mechanical properties—elastic moduli, Poisson ratios, and shear moduli. The model allows for analysis of how composites interact in order to design composites which gain full advantage of their properties.

Lithostratigraphy of the Kweekvlei Formation (Witteberg Group), Cape Supergroup

2017 ◽  
Vol 120 (3) ◽  
pp. 421-432 ◽  
Author(s):  
C. Browning ◽  
M. Reid
Keyword(s):  
South Africa ◽  
Transition Zone ◽  
Distal Part ◽  
Vascular Plant ◽  
Trace Fossil ◽  
Plant Debris ◽  
Lower Carboniferous ◽  
Fossil Assemblage ◽  
Low Diversity ◽  
Storm Wave

AbstractThe Lower Carboniferous, probably Tournaisian, Kweekvlei Formation is part of the Witteberg Group (Cape Supergroup) of South Africa. Together with the overlying Floriskraal Formation, it forms an upward-coarsening succession within the Lake Mentz Subgroup. Sedimentary features of the Kweekvlei Formation suggest deposition in a storm-wave dominated marine setting, within the storm-influenced, distal part of an offshore transition zone environment. This predominantly argillaceous formation preserves a low diversity trace fossil assemblage. Reworked vascular plant debris (including the problematic genus Praeramunculus sp.) and a shark spine have been reported for the Kweekvlei Formation. There are no known stratigraphic equivalents in South Africa.

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