Influence of Solid Solution Formation on the Solid State Sintering of Mgcr2O4

2014 ◽  
pp. 313-317
Author(s):  
Hamidreza Zargar ◽  
George Oprea ◽  
Tom Troczynski
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Solid Solution Formation ◽  
Solution Formation ◽  
Solid State Sintering

Solid State Amorphization and Alloy Parameters for High Entropy Alloys

2021 ◽  
Vol 1016 ◽  
pp. 990-996
Author(s):  
Takeshi Nagase
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Intermetallic Compounds ◽  
Electron Irradiation ◽  
Fast Electron ◽  
High Entropy Alloy ◽  
Solid Solution Formation ◽  
High Entropy ◽  
Solution Formation ◽  
State Amorphization

Fast electron irradiation can induce the solid-state amorphization (SSA) of many intermetallic compounds. The occurrence of SSA stimulated by fast electron irradiation was found in the Al0.5TiZrPdCuNi high-entropy alloy (HEA). The relationship between the occurrence of SSA in intermetallic compounds under fast electron irradiation and the empirical alloy parameters for predicting the solid-solution-formation tendency in HEAs was discussed. The occurrence of SSA in intermetallic compounds was hardly predicted, only by the alloy parameters of δ or ΔHmix, which have been widely used for predicting solid-solution formation in HEAs. All intermetallic compounds with ΔHmix ≤ -35 kJ/mol and those with δ ≥ 12.5 exhibit the occurrence of SSA. This implies that the intermetallic compounds with a largely negative ΔHmix value and a largely positive δ parameter are favorable for the occurrence of SSA.

scholarly journals Single crystal to single crystal [2+2] photoreactions in chloride and sulphate salts of 4-amino-cinnamic acid via solid-solution formation: a structural and kinetic study

2016 ◽  
Vol 52 (9) ◽  
pp. 1899-1902 ◽  
Author(s):  
Simone d'Agostino ◽  
Floriana Spinelli ◽  
Elisa Boanini ◽  
Dario Braga ◽  
Fabrizia Grepioni
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Single Crystal ◽  
Kinetic Study ◽  
Cinnamic Acid ◽  
State Solution ◽  
Solid Solution Formation ◽  
Solution Formation ◽  
Sulfate Salts ◽  
Sulphate Salts

SCSC [2+2] photodimerizationviathe formation of solid state solution is achieved in chloride and sulfate salts of 4-amino-cinnamic acid, and structural and kinetic analyses have been performed.

AEM investigation of ZrO2 solid solution formation in ZrO2/mullite composites

1984 ◽  
Vol 42 ◽  
pp. 408-409
Author(s):  
T. R. Dinger
Keyword(s):  
Solid Solution ◽  
Ion Beam ◽  
Analytical Electron Microscopy ◽  
Transformation Toughening ◽  
Solid Solution Formation ◽  
Solution Formation ◽  
Propagating Crack ◽  
Analytical Electron ◽  
Microcrack Toughening ◽  
Made In

Zirconia (ZrO2) is often added to ceramic compacts to increase their toughness. The mechanisms by which this toughness increase occurs are generally accepted to be those of transformation toughening and microcracking. The mechanism of transformation toughening is based on the presence of metastable tetragonal ZrO2 which transforms to the monoclinic allotrope when stressed by a propagating crack. The decrease in volume which accompanies this transformation effectively relieves the applied stress at the crack tip and toughens the material; microcrack toughening arises from the deflection of a propagating crack around sharply angular inclusions.These mechanisms, however, do not explain the toughness increases associated with the class of composites investigated here. Analytical electron microscopy (AEM) has been used to determine whether solid solution effects could be the cause of this increased toughness. Specimens of a mullite (3Al2O3·2SiO2) + 15 vol. % ZrO2 were prepared by the usual technique of mechanical thinning followed by ion beam milling. All observations were made in a Philips EM400 TEM/STEM microscope fitted with EDXS and EELS spectrometers.

SOLID SOLUTION FORMATION DURING LIQUID PHASE SINTERING

1986 ◽  
Vol 47 (C1) ◽  
pp. C1-441-C1-445
Author(s):  
E. KOSTIĆ ◽  
S. J. KISS ◽  
D. CEROVIĆ
Keyword(s):  
Solid Solution ◽  
Liquid Phase ◽  
Liquid Phase Sintering ◽  
Solid Solution Formation ◽  
Solution Formation

Structural basis of solid solution formation during chiral resolution

2000 ◽  
Vol 11 (20) ◽  
pp. 4061-4070 ◽  
Author(s):  
Orsolya Barabás ◽  
Dóra K Menyhárd ◽  
Zsolt Böcskei ◽  
Kálmán Simon ◽  
Ilona Kiss-Ajzert ◽  
...  
Keyword(s):  
Solid Solution ◽  
Chiral Resolution ◽  
Structural Basis ◽  
Solid Solution Formation ◽  
Solution Formation

Solid-State Synthesis of Magnesium Base Thermoelectric Alloys via Bulk Mechanical Alloying

2006 ◽  
Vol 980 ◽  
Author(s):  
Tatsuhiko Aizawa ◽  
Renbo Song
Keyword(s):  
Solid State ◽  
Mechanical Alloying ◽  
Binary Compound ◽  
Solid State Synthesis ◽  
Medium Temperature ◽  
Solid Solution Formation ◽  
Ternary Alloy Systems ◽  
Solution Formation ◽  
Diffusion Controlled ◽  
Electric Structure

AbstractMagnesium binary and ternary alloy systems have been popular as a thermoelectric light-weight alloy to be working in the medium temperature range. The solid-state reactivity via the bulk mechanical alloying is applied to yield these types of alloys. The diffusion-controlled solid-state synthesis is first stated as a process to yield a binary compound, Mg2X (X = Ge, Sn and Pb). This processing is further applied to directly synthesize several ternary thermoelectric alloys Mg2Si1-xGex, Mg2Si1-ySny and Mg2Sn1-zPbz for 0.0 < x, y, z < 1.0 and to evaluate their thermoelectric properties. Hot pressing is used to make full-dense billets and samples for thermoelectric measurement. The effect of germanium and tin contents on their Seebeck coefficient and band-gap is investigated to describe the p-n transition behavior and to understand the change of electric structure with solid solution formation.

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