Design and Architecture of Nanostructured Heterogeneous Catalysts for CO 2 Hydrogenation to Formic Acid/Formate

2021 ◽  
pp. 179-205
Author(s):  
Kohsuke Mori ◽  
Hiromi Yamashita
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalysts

In situ FT-IR Investigation of Formic Acid Adsorption on Reduced and Reoxidized Copper Catalysts

1994 ◽  
Vol 48 (7) ◽  
pp. 827-832 ◽  
Author(s):  
Graeme J. Millar ◽  
David Newton ◽  
Graham A. Bowmaker ◽  
Ralph P. Cooney
Keyword(s):  
Activation Energy ◽  
Formic Acid ◽  
Maximum Rate ◽  
Heterogeneous Catalysts ◽  
Copper Catalyst ◽  
Copper Catalysts ◽  
Copper Surface ◽  
Desorption Activation Energy ◽  
Ft Ir

An in situ infrared cell capable of studying reactions over heterogeneous catalysts in the temperature range 77 to 773 K has been designed. In particular, the adsorption of formic acid on a model Cu/SiO2 methanol synthesis catalyst was investigated. Exposure of a reduced copper surface to formic acid at 300 K resulted in the formation of both formic acid molecules, which were ligated to the copper catalyst, and chemisorbed bidentate copper formate species. Under temperature-programming conditions, the bidentate species displayed a maximum rate of desorption at 433 K, which correlates to a desorption activation energy of 120 kJ mol−1. In contrast, on the reoxidized catalyst, unidentate formate species were preferentially formed. These exhibited a maximum rate of desorption at a temperature of 408 K, and a desorption activation energy of 113 kJ mol−1. A mechanism was postulated to explain this behavior, and evidence was presented to show that useful kinetic data can be obtained for desorption from a catalyst in the form of a pressed disk.

Recent developments in the catalytic hydrogenation of CO2 to formic acid/formate using heterogeneous catalysts

2016 ◽  
Vol 3 (7) ◽  
pp. 882-895 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Kwangho Park ◽  
Kwang-Deog Jung ◽  
Sungho Yoon
Keyword(s):  
Formic Acid ◽  
Catalytic Hydrogenation ◽  
Heterogeneous Catalysts ◽  
Hydrogenation Of Co2 ◽  
Recent Developments ◽  
Recent Trends ◽  
Heterogeneous Hydrogenation ◽  
Hydrogenation Of Co

This review highlights the recent trends in the heterogeneous hydrogenation of CO2 to formic acid/formate.

scholarly journals Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content

Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1516
Author(s):  
B. Faroldi ◽  
M. A. Paviotti ◽  
M. Camino-Manjarrés ◽  
S. González-Carrazán ◽  
C. López-Olmos ◽  
...  
Keyword(s):  
Formic Acid ◽  
Photoelectron Spectroscopy ◽  
Noble Metals ◽  
Heterogeneous Catalysts ◽  
Earth Metal ◽  
Major Product ◽  
Catalytic Dehydrogenation ◽  
Acid Decomposition ◽  
X Ray ◽  
Formic Acid Decomposition

Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by incipient wet impregnation. The effect of doping with an alkaline earth metal (calcium) was studied, and the solids were tested in the formic acid decomposition reaction to produce hydrogen. The catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and programmed temperature surface reaction (TPSR). The catalyst doped with 19.3 wt.% of Ca showed 100% conversion of formic acid at 160 °C, with a 92% of selectivity to hydrogen. In addition, all the tested materials were promising for their application, since they showed catalytic behaviors (conversion and selectivity to hydrogen) comparable to those of noble metals reported in the literature.

A Simple and Effective Principle for a Rational Design of Heterogeneous Catalysts for Dehydrogenation of Formic Acid

2019 ◽  
Vol 31 (15) ◽  
pp. 1806781 ◽  
Author(s):  
Si‐Jia Li ◽  
Yi‐Tong Zhou ◽  
Xia Kang ◽  
Dong‐Xue Liu ◽  
Lin Gu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Rational Design ◽  
Heterogeneous Catalysts

Room-temperature transfer hydrogenation and fast separation of unsaturated compounds over heterogeneous catalysts in an aqueous solution of formic acid

2014 ◽  
Vol 16 (8) ◽  
pp. 3746-3751 ◽  
Author(s):  
Ling-Hong Gong ◽  
Yi-Yu Cai ◽  
Xin-Hao Li ◽  
Ya-Nan Zhang ◽  
Juan Su ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Room Temperature ◽  
Heterogeneous Catalysts ◽  
Transfer Hydrogenation ◽  
Unsaturated Compounds ◽  
Fast Separation

Transfer hydrogenation of unsaturated compounds can be conducted over Pd/CN catalysts at room temperature in an aqueous solution of formic acid.

Automatic high-pressure hydrogen generation from formic acid in the presence of nano-Pd heterogeneous catalysts at mild temperatures

2017 ◽  
Vol 1 (5) ◽  
pp. 1049-1055 ◽  
Author(s):  
Heng Zhong ◽  
Masayuki Iguchi ◽  
Fu-Zhan Song ◽  
Maya Chatterjee ◽  
Takayuki Ishizaka ◽  
...  
Keyword(s):  
High Pressure ◽  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Heterogeneous Catalysts ◽  
Hydrogen Generation ◽  
Catalyst System ◽  
First Report ◽  
System P ◽  
Pressure Hydrogen

First report of an automatic high pressure hydrogen generation from HCOOH with a heterogeneous catalyst system.

scholarly journals New Approaches Toward the Hydrogen Production From Formic Acid Dehydrogenation Over Pd-Based Heterogeneous Catalysts

2019 ◽  
Vol 6 ◽  
Author(s):  
Miriam Navlani-García ◽  
Kohsuke Mori ◽  
David Salinas-Torres ◽  
Yasutaka Kuwahara ◽  
Hiromi Yamashita
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Heterogeneous Catalysts ◽  
New Approaches ◽  
Formic Acid Dehydrogenation

scholarly journals Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom

2021 ◽  
Author(s):  
Ruiyan Sun ◽  
Yuhe Liao ◽  
Shao-Tao Bai ◽  
Mingyuan Zheng ◽  
Cheng Zhou ◽  
...  
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalysts ◽  
Co2 Hydrogenation ◽  
Single Atom ◽  
Structure Activity

This review provides an overview of advances on constructing heterogeneous nanostructured and single atom catalysts for CO2 hydrogenation to formic acid/formate. The main focus is placed on structure–activity correlations and mechanistic insights.

scholarly journals Formic Acid‐Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts

2018 ◽  
Vol 2 (2) ◽  
pp. 1700161 ◽  
Author(s):  
Heng Zhong ◽  
Masayuki Iguchi ◽  
Maya Chatterjee ◽  
Yuichiro Himeda ◽  
Qiang Xu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalysts ◽  
Carrier System ◽  
Hydrogen Carrier
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