Tuning the Work Function of Polar Zinc Oxide Surfaces using Modified Phosphonic Acid Self‐Assembled Monolayers

2014 ◽  
Vol 24 (44) ◽  
pp. 7014-7024 ◽  
Author(s):  
Ilja Lange ◽  
Sina Reiter ◽  
Michael Pätzel ◽  
Anton Zykov ◽  
Alexei Nefedov ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Work Function ◽  
Phosphonic Acid ◽  
Self Assembled Monolayers ◽  
Oxide Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Effect of time and deposition method on quality of phosphonic acid modifier self-assembled monolayers on indium zinc oxide

2016 ◽  
Vol 389 ◽  
pp. 190-198 ◽  
Author(s):  
Lingzi Sang ◽  
Kristina M. Knesting ◽  
Anuradha Bulusu ◽  
Ajaya K. Sigdel ◽  
Anthony J. Giordano ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Phosphonic Acid ◽  
Self Assembled Monolayers ◽  
Deposition Method ◽  
Indium Zinc Oxide ◽  
Assembled Monolayers ◽  
Self Assembled

PM-IRRAS Determination of Molecular Orientation of Phosphonic Acid Self-Assembled Monolayers on Indium Zinc Oxide

Langmuir ◽  
2015 ◽  
Vol 31 (20) ◽  
pp. 5603-5613 ◽  
Author(s):  
Lingzi Sang ◽  
Anoma Mudalige ◽  
Ajaya K. Sigdel ◽  
Anthony J. Giordano ◽  
Seth R. Marder ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Phosphonic Acid ◽  
Molecular Orientation ◽  
Self Assembled Monolayers ◽  
Indium Zinc Oxide ◽  
Assembled Monolayers ◽  
Self Assembled

Characterizing the Molecular Order of Phosphonic Acid Self-Assembled Monolayers on Indium Tin Oxide Surfaces

Langmuir ◽  
2011 ◽  
Vol 27 (19) ◽  
pp. 11883-11888 ◽  
Author(s):  
Mark D. Losego ◽  
Joshua T. Guske ◽  
Alina Efremenko ◽  
Jon-Paul Maria ◽  
Stefan Franzen
Keyword(s):  
Tin Oxide ◽  
Phosphonic Acid ◽  
Indium Tin Oxide ◽  
Self Assembled Monolayers ◽  
Oxide Surfaces ◽  
Molecular Order ◽  
Assembled Monolayers ◽  
Self Assembled

Work function shifts of a zinc oxide surface upon deposition of self-assembled monolayers: a theoretical insight

2014 ◽  
Vol 16 (38) ◽  
pp. 20887-20899 ◽  
Author(s):  
D. Cornil ◽  
T. Van Regemorter ◽  
D. Beljonne ◽  
J. Cornil
Keyword(s):  
Zinc Oxide ◽  
Work Function ◽  
Self Assembled Monolayers ◽  
Oxide Surface ◽  
Benzoic Acids ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Theoretical Insight ◽  
The Way

We have investigated at the DFT level the way the work function of ZnO is affected upon deposition of self-assembled monolayers made of 4-tert-butylpyridine and various benzoic acids.

Photoswitching in azobenzene self-assembled monolayers capped on zinc oxide: Nanodots vs nanorods

2012 ◽  
Vol 367 (1) ◽  
pp. 109-114 ◽  
Author(s):  
Syed Mujtaba Shah ◽  
Cyril Martini ◽  
Jörg Ackermann ◽  
Frédéric Fages
Keyword(s):  
Zinc Oxide ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Self-Assembled Monolayers of 12-Mercaptododecylphosphonic Acid on Titania Particles; Application to the Extraction of Heavy Metals

2004 ◽  
Vol 847 ◽  
Author(s):  
Sébastien Anthérieu ◽  
Florence Brodard-Séverac ◽  
Gilles Guerrero ◽  
P. Hubert Mutin
Keyword(s):  
Heavy Metals ◽  
Chemical Analysis ◽  
Phosphonic Acid ◽  
Metal Extraction ◽  
Self Assembled Monolayers ◽  
Extraction Ability ◽  
Self Assembled Monolayer ◽  
Inorganic Hybrid ◽  
Assembled Monolayers ◽  
Self Assembled

ABSTRACTTitania particles (P25 DEGUSSA AG) were treated by a solution of 12-mercaptododecyl-phosphonic acid (MDPA) in toluene to obtain an organic-inorganic hybrid material with thiol functions at the surface. This material was characterized by chemical analysis, solid state 31P MAS NMR and FTIR spectroscopies, and XPS. Reaction of the phosphonic acid end of MDPA with the TiO2 surface led to the formation of a relatively dense and well-ordered self-assembled monolayer (SAM), with a density of about 3.9 SH functions per nm2. This material was tested for the extraction of mercury in water at pH 7, 9, and 11. Chemical analysis indicated no loss of SH functionality, even at pH 11. The best extraction results were obtained at pH 9 and 11, with a metal extraction ability between 85 and 90%.

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