Bright White-Light Emission from Semiconductor Nanocrystals: by Chance and by Design

2007 ◽  
Vol 19 (4) ◽  
pp. 569-572 ◽  
Author(s):  
S. Sapra ◽  
S. Mayilo ◽  
T. A. Klar ◽  
A. L. Rogach ◽  
J. Feldmann
2007 ◽  
Vol 19 (4) ◽  
pp. NA-NA
Author(s):  
S. Sapra ◽  
S. Mayilo ◽  
T. A. Klar ◽  
A. L. Rogach ◽  
J. Feldmann

ChemInform ◽  
2012 ◽  
Vol 43 (36) ◽  
pp. no-no
Author(s):  
Teresa E. Rosson ◽  
Sarah M. Claiborne ◽  
James R. McBride ◽  
Benjamin S. Stratton ◽  
Sandra J. Rosenthal

2021 ◽  
Vol 122 ◽  
pp. 111705
Author(s):  
W. Rittisut ◽  
N. Wantana ◽  
Y. Ruangtaweep ◽  
P. Mool-am-kha ◽  
J. Padchasri ◽  
...  

2019 ◽  
Vol 787 ◽  
pp. 1120-1127 ◽  
Author(s):  
Dandan Ju ◽  
Feng Song ◽  
Yingdong Han ◽  
Jun Zhang ◽  
Feifei Song ◽  
...  

2012 ◽  
Vol 134 (19) ◽  
pp. 8006-8009 ◽  
Author(s):  
Teresa E. Rosson ◽  
Sarah M. Claiborne ◽  
James R. McBride ◽  
Benjamin S. Stratton ◽  
Sandra J. Rosenthal

2014 ◽  
Vol 6 (4) ◽  
pp. 1-17 ◽  
Author(s):  
G. Bilir ◽  
G. Ozen ◽  
J. Collins ◽  
M. Cesaria ◽  
B. Di Bartolo

2020 ◽  
Author(s):  
Shilpi Jaiswal ◽  
Jyotsana Pathak ◽  
Abhijit Patra

Semiconductor nanocrystals are promising for display and lighting devices. Herein, we report a facile one-pot synthetic route to fabricate white light emitting CdSexSy nanocrystals with enhanced quantum yield using CdO, S powder, and Se powder as precursors. The phosphine-free route was adopted, employing paraffin oil as the reducing agent and solvent for the fabrication. The optical properties can be effectively tailored by controlling the reaction time and the molar ratio of Se/S. The emission of pristine CdSexSy nanocrystals covered a broad visible range from 400 to 750 nm. The CdSexSy nanocrystals (Se/S = 0.4) exhibited white-light emission with quantum yield of 50 ± 3 % and Commission Internationale de l'Eclairage (CIE) chromaticity coordinates of (0.30, 0.31). The band-edge (~400-450 nm) to trap-state (~550-750 nm) emissions was tuned by controlling the Se/S ratio, and the different shades of white light were obtained. Furthermore, the quantum yield and CIE coordinates of the CdSexSy nanocrystals (Se/S = 0.4) were found to be similar even after 30 days of fabrication, showing the high stability of nanocrystals. The white light emission was retained in nanocrystals-embedded poly(methyl methacrylate) (PMMA) thin film and also in the hydrogel matrix. The one-pot, low-cost, scalable fabrication of white light emitting CdSexSy nanocrystals demonstrated in the present study offers promising scope in the solid-state display applications. <br>


2021 ◽  
Vol 7 (34) ◽  
pp. eabg3989
Author(s):  
Jun-Hua Wei ◽  
Jin-Feng Liao ◽  
Lei Zhou ◽  
Jian-Bin Luo ◽  
Xu-Dong Wang ◽  
...  

Although single-source white emissive perovskite has emerged as a class of encouraging light-emitting material, the synthesis of lead-free halide perovskite materials with high luminous efficiency is still challenging. Here, we report a series of zero-dimensional indium-antimony (In/Sb) alloyed halide single crystals, BAPPIn2–2xSb2xCl10 (BAPP = C10H28N4, x = 0 to 1), with tunable emission. In BAPPIn1.996Sb0.004Cl10, bright yellow emission with near 100% photoluminescence quantum yield (PLQY) is yielded when it was excited at 320 nm, which turns into bright white-light emission with a PLQY of 44.0% when excited at 365 nm. Combined spectroscopy and theoretical studies reveal that the BAPP4+-associated blue emission and inorganic polyhedron–afforded orange emission function as a perfect pair of complementary colors affording white light in BAPPIn1.996Sb0.004Cl10. Moreover, the interesting afterglow behavior, together with excitation-dependent emission property, makes BAPPIn2–2xSb2xCl10 as high-performance anti-counterfeiting/information storage materials.


Sign in / Sign up

Export Citation Format

Share Document