Transparent Thermotherapeutic Skin Patch Based on Highly Conductive and Stretchable Copper Mesh Heater

Close observation of various attachment systems in animal skins has revealed various exquisite multi-scale architectures for essential functions such as locomotion, crawling, mating, and protection from predators. Some of these adhesion systems of geckos and beetles have unique structural features (e.g. high-aspect ratio, tilted angle, and hierarchical nanostructure), resulting in mechanical interlocking mediated by van der Waals forces or liquid secretion (capillary force). In this chapter, we present an overview of recent advances in bio-inspired, artificial dry adhesives, and biomimetics in the context of nanofabrication and material properties. In addition, relevant bio-inspired structural materials, devices (clean transportation device, interlocker, biomedical skin patch, and flexible strain-gauge sensor) and microrobots are briefly introduced, which would shed light on future smart, directional, and reversible adhesion systems.

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Dodecyl Mercaptan Functionalized Copper Mesh for Water Repellence and Oil-water Separation

Journal of Bionic Engineering ◽

10.1007/s42235-021-0062-7 ◽

2021 ◽

Vol 18 (4) ◽

pp. 887-899

Author(s):

Yanling Tian ◽

Jiekai Feng ◽

Zexin Cai ◽

Jiaqi Chao ◽

Dawei Zhang ◽

...

Keyword(s):

Separation Efficiency ◽

Synthesis Process ◽

Water Separation ◽

Oil Water Separation ◽

One Step ◽

Oil Water ◽

Water Repellence ◽

Copper Mesh ◽

Dodecyl Mercaptan

AbstractReckless discharge of industrial wastewater and domestic sewage as well as frequent leakage of crude oil have caused serious environmental problems and posed severe threat to human survival. Various nature inspired superhy-drophobic surfaces have been successfully applied in oily water remediation. However, further improvements are still urgently needed for practical application in terms of facile synthesis process and long-term durability towards harsh environment. Herein, we propose a simple one-step dodecyl mercaptan functionalization method to fabricate Super-hydrophobic-Superoleophilic Copper Mesh (SSCM). The prepared SSCM possesses excellent water repellence and oil affinity, enabling it to successfully separate various oil-water mixtures with high separation efficiency (e.g., > 99% for hexadecane-water mixture). The SSCM retains high separating ability when hot water and strong corrosive aqueous solutions are used to simulate oil-water mixtures, indicating remarkable chemical durability of the dodecyl mercaptan functionalized copper mesh. Additionally, the efficiency can be well maintained during 50 cycles of separation, and the water repellence is even stable after storage in air for 120 days, demonstrating the reusability and long-term stability of the SSCM. Furthermore, the functionalized mesh also shows good mechanical robustness towards abrasion by sandpaper, and oil-water separation efficiency of > 96% can be obtained after 10 cycles of abrasion. The reported one-step dodecyl mercaptan functionalization could be a simple method for increasing the water repellence of copper mesh, and thereby be a great candidate for treating large-scale oily wastewater in harsh environments.

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