Surface Local Polarization Induced by Bismuth‐Oxygen Vacancy Pairs Tuning Non‐Covalent Interaction for CO 2 Photoreduction

2021 ◽  
pp. 2102389
Author(s):  
Jun Di ◽  
Chao Chen ◽  
Chao Zhu ◽  
Ran Long ◽  
Hailong Chen ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Covalent Interaction ◽  
Local Polarization

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

Synthesis and tubulin interaction of thiocolchicines containing an isothiocyanato group. Synthesis of C(2)-deuterated and C(2)-14C-labeled 7-isothiocyanatodeacetamidothiocolchicine

1991 ◽  
Vol 56 (11) ◽  
pp. 2306-2312 ◽  
Author(s):  
Anjum Muzaffar ◽  
Ernest Hamel ◽  
Rouli Bai ◽  
Arnold Brossi
Keyword(s):  
Binding Site ◽  
Covalent Bond ◽  
Tubulin Polymerization ◽  
Low Concentration ◽  
Covalent Interaction ◽  
Isotope Label ◽  
Colchicine Binding Site

Synthesis of isothiocyanato substituted thiocolchicines XI - XIV is described. Introduction of an isotope label is demonstrated with the deuterated isothiocyanate XII and the 14C-labeled analog XIII. These isothiocyanates inhibit tubulin polymerization at low concentration. In addition, the 14C-labeled XIII forms covalent bond(s) with tubulin. Unfortunately, the covalent reaction while rapid, is not inhibited by preincubation of tubulin with colchicine. The covalent interaction of XIII with tubulin thus appears to be nonspecific, limiting its use as a marker of the colchicine binding site on tubulin.

Enhanced photocatalytic activity of perovskite NaNbO3 by oxygen vacancy engineering

2019 ◽  
Vol 21 (22) ◽  
pp. 11697-11704 ◽  
Author(s):  
Bian Yang ◽  
Jihong Bian ◽  
Lei Wang ◽  
Jianwei Wang ◽  
Yaping Du ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Oxygen Vacancy

Oxygen vacancy engineering can improve the photocatalytic activity of perovskite NaNbO3.

Improvement of reliability of polymer nanocomposite based transparent memory device by oxygen vacancy rich ZnO nanorods

2016 ◽  
Vol 164 ◽  
pp. 53-58 ◽  
Author(s):  
Snigdha Bhattacharjee ◽  
Pranab Kumar Sarkar ◽  
Nandini Roy ◽  
Asim Roy
Keyword(s):  
Oxygen Vacancy ◽  
Zno Nanorods ◽  
Polymer Nanocomposite ◽  
Memory Device

Oxygen Vacancy Engineering in Fe Doped Akhtenskite-Type MnO2 for Low-Temperature Toluene Oxidation

2020 ◽  
pp. 119873
Author(s):  
Yu Wang ◽  
Ji Wu ◽  
Gang Wang ◽  
Dengyao Yang ◽  
Tatsumi Ishihara ◽  
...  
Keyword(s):  
Low Temperature ◽  
Oxygen Vacancy ◽  
Toluene Oxidation

Boosted charge transfer in oxygen vacancy-rich K+ birnessite MnO2 for water oxidation and zinc-ion batteries

2021 ◽  
Vol 378 ◽  
pp. 138147
Author(s):  
MengXian Lin ◽  
Fuqiang Shao ◽  
Shuting Weng ◽  
Shanshan Xiong ◽  
Shuai Liu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Oxygen Vacancy ◽  
Water Oxidation ◽  
Zinc Ion

Efficient degradation of ciprofloxacin by magnetic γ-Fe2O3-MnO2 with oxygen vacancy in visible-light/peroxymonosulfate system

Chemosphere ◽  
2021 ◽  
pp. 130257
Author(s):  
Jianhui Zhao ◽  
Yuanzhou Wang ◽  
Ning Li ◽  
Shaopo Wang ◽  
Junli Yu ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Visible Light
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