scholarly journals Carbonate Electrolytes: Fluorinated Carbonate Electrolyte with Superior Oxidative Stability Enables Long‐Term Cycle Stability of Na 2/3 Ni 1/3 Mn 2/3 O 2 Cathodes in Sodium‐Ion Batteries (Adv. Energy Mater. 9/2021)

2021 ◽  
Vol 11 (9) ◽  
pp. 2170034
Author(s):  
Shuilin Wu ◽  
Bizhe Su ◽  
Kun Ni ◽  
Fei Pan ◽  
Changlai Wang ◽  
...  
2020 ◽  
Vol 12 (39) ◽  
pp. 43624-43633
Author(s):  
Qian Liu ◽  
Shao-Jian Zhang ◽  
Cheng-Cheng Xiang ◽  
Chen-Xu Luo ◽  
Peng-Fang Zhang ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (46) ◽  
pp. 28488-28495
Author(s):  
Yucheng Zhu ◽  
Haoyu Li ◽  
Yuanming Wu ◽  
Liwen Yang ◽  
Yan Sun ◽  
...  

The capacity rising is due to the biphasic coexistence of MoS2 during the cycling and the progressive increase in the 1T-MoS2 content. Simultaneously, the layer spacing expanded from 0.62 nm to 1.03 nm during the cycling process.


Author(s):  
Lisan Cui ◽  
Chunlei Tan ◽  
Yu Li ◽  
Qichang Pan ◽  
Lixuan Zhang ◽  
...  

2016 ◽  
Vol 26 (11) ◽  
pp. 1777-1786 ◽  
Author(s):  
Chengliang Wang ◽  
Yaoguo Fang ◽  
Yang Xu ◽  
Liying Liang ◽  
Min Zhou ◽  
...  

2015 ◽  
Vol 3 (43) ◽  
pp. 21478-21485 ◽  
Author(s):  
Qiang Liu ◽  
Dongxue Wang ◽  
Xu Yang ◽  
Nan Chen ◽  
Chunzhong Wang ◽  
...  

The HRTEM image and long-term cycle life with capacity retentions of 70% and 50% over 1000 and 3000 cycles at 10C and 30C rates, respectively.


2017 ◽  
Vol 27 (2) ◽  
pp. 143 ◽  
Author(s):  
Tan Anh Ta ◽  
Long Duy Pham ◽  
Hieu Sy Nguyen ◽  
Chung Vu Hoang ◽  
Chi Ha Le ◽  
...  

Orthorhombic Na0.44MnO2 with an S-shape tunnel structure was successfully synthesized by a hydrothermal method. The Na0.44MnO2 material has lattice parameters of a = 9.0842 Å, b = 26.2889 Å, and c = 2.8245 Å. Scanning electron microscope analysis reveals that the morphologies of Na0.44MnO2 consist of Na0.44MnO2 nanowires with diameters of about 30-50 nm and Na0.44MnO2 particles with the size in the range of 200 to 500 nm. The first charge and discharge capacities of Na0.44MnO2 cathode, at 0.1 C between 2.0-4.0 V, are 66.2 mAh g-1 and 62.7 mAh g-1, respectively. The Na0.44MnO2 has an excellent cycle stability with 85.3% of capacity retention over 50 cycles. The coulombic efficiency of Na0.44MnO2 material is approximately 90% after 70 cycles. It is suggested that the structure of Na0.44MnO2 is stable during cycling and Na0.44MnO2 can be a promising cathode material for sodium ion batteries.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4331
Author(s):  
Volodymyr Pavlyuk ◽  
Wojciech Ciesielski ◽  
Nazar Pavlyuk ◽  
Damian Kulawik ◽  
Agnieszka Balińska ◽  
...  

The maximally disordered (MD) phases with the general formula Y5−xPrxSb3−yMy (M = Sn, Pb) are formed with partial substitution of Y by Pr and Sb by Sn or Pb in the binary Y5Sb3 compound. During the electrochemical lithiation and sodiation, the formation of Y5-xPrxSb3-yMyLiz and Y5−xPrxSb3−yMyNaz maximally disordered–high entropy intermetallic phases (MD-HEIP), as the result of insertion of Li/Na into octahedral voids, were observed. Carbon nanotubes (CNT) are an effective additive to improve the cycle stability of the Y5−xPrxSb3−yMy (M = Sn, Pb) anodes for lithium-ion (LIBs) and sodium-ion batteries (SIBs). Modification of Y5−xPrxSb3−ySny alloys by carbon nanotubes allowed us to significantly increase the discharge capacity of both types of batteries, which reaches 280 mAh · g−1 (for LIBs) and 160 mAh · g−1 (for SIBs), respectively. For Y5−xPrxSb3−yPby alloys in which antimony is replaced by lead, these capacities are slightly smaller and are 270 mAh · g−1 (for LIBs) and 155 mAh · g−1 (for SIBs), respectively. Results show that structure disordering and CNT additives could increase the electrode capacities up to 30% for LIBs and up to 25% for SIBs.


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