An Electrochemically Activated Nanofilm for Sustainable Mg Anode with Fast Charge Transfer Kinetics

Highly reversible Mg plating/stripping is key for rechargeable Mg batteries and has typically been successfully demonstrated using transient electrochemical techniques such as cyclic voltammetry measurements. However, little effort has been invested in studying the stability of the electrode/electrolyte interface over an extended time. We report here the development an in situ generated surface film for Mg anodes based on electrodeposited bismuth (E_Bi). This film improves the interfacial stability of Mg in contact with the electrolyte, particularly over an extended time, and possesses fast charge-transfer kinetics (< 30 Ω∙cm2) and low non-time-sensitive interfacial film resistance (ca. 5 Ω∙cm2) for active Mg species.

Performance of an Environmentally Friendly Alternative Fluid in a Loop Heat Pipe-Based Battery Thermal Management System

The present investigation aims to devise a thermal management system (TMS) for electric vehicles able to improve on limitations like charging time and all-electric range, together with the safety and environmental impact of the chosen thermal medium. A research gap is identified, as focus is often on addressing system thermal performance without considering that the thermal medium must not only provide suitable performances, but also must not add risks to both passengers and the environment. Thus, this work proposes an innovative cooling system including graphite sheets and a Loop Heat Pipe, filled with Novec™ 649 as working fluid, due to its exceptional environmental properties (GWP = 1 − ODP = 0) and safety features (non-flammable, non-toxic, dielectric). A three-cell module experimental demonstrator was built to compare temperatures when the proposed TMS is run with Novec™ 649 and ethanol. Results of testing over a bespoke fast charge driving cycle show that Novec™ 649 gave a faster start-up and a slightly higher maximum temperature (0.7 °C), meaning that the gains in safety and lower environmental impact brought by Novec™ 649 came without lowering the thermal performance. Finally, the TMS was tested under three different fast charge conditions (1C, 2C, 3C), obtaining maximum temperatures of 28.4 °C, 36.3 °C and 46.4 °C, respectively.

Formation of a Fast Charge Transfer Channel in Quasi-2D Perovskite Solar Cells through External Electric Field Modulation

Quasi-2D perovskites solar cells exhibit excellent environmental stability, but relatively low photovoltaic properties, compared with 3D perovskites solar cells. However, charge transport and extraction in quasi-2D perovskite solar cells are still limited by the inevitable quantum well effect, resulting in low power conversion efficiency (PCE). To date, most efforts concentrate on crystal orientation and favorable alignment during materials and films processing. In this paper, we demonstrated that the quasi-2D perovskite [(BA)2(MA)3Pb4I13 (n = 4)] solar cells show an optimized device performance through forming a fast charge transfer channel among 2D quantum wells through external electric field modulation, with appropriate modulation bias and time after the device has been fabricated. Essentially, ions will move directionally due to local polarization in quasi-2D perovskite solar cells under the action of electric field modulation. More importantly, the mobile ions function as a dopant to de-passivate the defects when releasing at grain boundaries, while decreasing built-in potential by applying forward modulation bias with proper modulation time. The capacitance-voltage characteristics indicate that electric field modulation can decrease the charge accumulation and improve the charge collection in quasi-2D perovskite solar cells. Photoluminescence (PL) studies confirm that the non-radiative recombination is reduced by electric field modulation, leading to enhanced charge transfer. Our work indicates that external electric field modulation is an effective method to form a fast charge transfer channel among 2D quantum wells, leading to enhanced charge transfer and charge collection through local polarization toward developing high–performance quasi-2D perovskite devices.