Selective Carbonylation of Dimethyl Ether to Methyl Acetate Catalyzed by Acidic Zeolites

2006 ◽  
Vol 45 (10) ◽  
pp. 1617-1620 ◽  
Author(s):  
Patricia Cheung ◽  
Aditya Bhan ◽  
Glenn J. Sunley ◽  
Enrique Iglesia
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Acidic Zeolites

Selective Carbonylation of Dimethyl Ether to Methyl Acetate Catalyzed by Acidic Zeolites

2006 ◽  
Vol 118 (10) ◽  
pp. 1647-1650 ◽  
Author(s):  
Patricia Cheung ◽  
Aditya Bhan ◽  
Glenn J. Sunley ◽  
Enrique Iglesia
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Acidic Zeolites

Carbonylation of dimethyl ether over Co-HMOR

2018 ◽  
Vol 8 (8) ◽  
pp. 2124-2130 ◽  
Author(s):  
Meng Ma ◽  
Ensheng Zhan ◽  
Xiumin Huang ◽  
Na Ta ◽  
Zhiping Xiong ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate

Incorporation of Co2+ into the framework of HMOR significantly enhanced the activity for the carbonylation of dimethyl ether to methyl acetate.

A brand new zeolite catalyst for carbonylation reaction

2019 ◽  
Vol 55 (8) ◽  
pp. 1048-1051 ◽  
Author(s):  
Xiaobo Feng ◽  
Jie Yao ◽  
Hangjie Li ◽  
Yuan Fang ◽  
Yoshiharu Yoneyama ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Zeolite Catalyst ◽  
Catalytic Performance ◽  
Carbonylation Reaction

EU-12 zeolite was discovered to posses unreported catalytic performance for carbonylation reaction converting dimethyl ether to methyl acetate.

Vapor phase carbonylation of dimethyl ether and methyl acetate with nickel-active carbon catalysts

1983 ◽  
Vol 7 (3) ◽  
pp. 361-368 ◽  
Author(s):  
Tsutomu Shikada ◽  
Kaoru Fujimoto ◽  
Michiharu Miyauchi ◽  
Hiro-o Tominaga
Keyword(s):  
Dimethyl Ether ◽  
Vapor Phase ◽  
Active Carbon ◽  
Methyl Acetate ◽  
Carbon Catalysts

Simultaneous carbonylation and homologation of dimethyl ether and homologation of methyl acetate to ethyl acetate in the presence of ruthenium catalysts

1978 ◽  
Vol 100 (19) ◽  
pp. 6238-6240 ◽  
Author(s):  
Giuseppe Braca ◽  
Glauco Sbrana ◽  
Giorgio Valentini ◽  
Giampaolo Andrich ◽  
Guglielmo Gregorio
Keyword(s):  
Ethyl Acetate ◽  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Ruthenium Catalysts

scholarly journals Reaction mechanism of dimethyl ether carbonylation to methyl acetate over mordenite – a combined DFT/experimental study

2017 ◽  
Vol 7 (5) ◽  
pp. 1141-1152 ◽  
Author(s):  
D. B. Rasmussen ◽  
J. M. Christensen ◽  
B. Temel ◽  
F. Studt ◽  
P. G. Moses ◽  
...  
Keyword(s):  
Experimental Study ◽  
Dimethyl Ether ◽  
Density Functional ◽  
Methyl Acetate ◽  
Flow Reactor ◽  
Reaction Path ◽  
Fixed Bed ◽  
Density Functional Theory Calculations ◽  
Membered Ring ◽  
Functional Theory

Dimethyl ether carbonylation to methyl acetate over mordenite was studied theoretically with density functional theory calculations and experimentally in a fixed bed flow reactor. A new reaction path to methyl acetate entirely in the 8 membered ring was discovered.

Promotion effect of Fe in mordenite zeolite on carbonylation of dimethyl ether to methyl acetate

2015 ◽  
Vol 5 (3) ◽  
pp. 1961-1968 ◽  
Author(s):  
Hui Zhou ◽  
Wenliang Zhu ◽  
Lei Shi ◽  
Hongchao Liu ◽  
Shiping Liu ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Promotion Effect ◽  
Carbonylation Reaction ◽  
The Stability

Fe-modified mordenite samples were synthesized and employed in dimethyl ether carbonylation reaction, resulting in an evident improvement of the stability.

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