scholarly journals Achieving Atomic Dispersion of Highly Loaded Transition Metals in Small‐Pore Zeolite SSZ‐13: High‐Capacity and High‐Efficiency Low‐Temperature CO and Passive NO x Adsorbers

2018 ◽  
Vol 57 (51) ◽  
pp. 16672-16677 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Nicholas R. Jaegers ◽  
Libor Kovarik ◽  
Jonathan C. Hanson ◽  
Franklin (Feng) Tao ◽  
...  
2018 ◽  
Vol 130 (51) ◽  
pp. 17152-17152 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Nicholas R. Jaegers ◽  
Libor Kovarik ◽  
Jonathan C. Hanson ◽  
Franklin (Feng) Tao ◽  
...  

2018 ◽  
Vol 130 (51) ◽  
pp. 16914-16919 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Nicholas R. Jaegers ◽  
Libor Kovarik ◽  
Jonathan C. Hanson ◽  
Franklin (Feng) Tao ◽  
...  

2021 ◽  
Vol 13 (7) ◽  
pp. 3617
Author(s):  
Agnieszka Medyńska-Juraszek ◽  
Agnieszka Latawiec ◽  
Jolanta Królczyk ◽  
Adam Bogacz ◽  
Dorota Kawałko ◽  
...  

Biochar application is reported as a method for improving physical and chemical soil properties, with a still questionable impact on the crop yields and quality. Plant productivity can be affected by biochar properties and soil conditions. High efficiency of biochar application was reported many times for plant cultivation in tropical and arid climates; however, the knowledge of how the biochar affects soils in temperate climate zones exhibiting different properties is still limited. Therefore, a three-year-long field experiment was conducted on a loamy Haplic Luvisol, a common arable soil in Central Europe, to extend the laboratory-scale experiments on biochar effectiveness. A low-temperature pinewood biochar was applied at the rate of 50 t h−1, and maize was selected as a tested crop. Biochar application did not significantly impact the chemical soil properties and fertility of tested soil. However, biochar improved soil physical properties and water retention, reducing plant water stress during hot dry summers, and thus resulting in better maize growth and higher yields. Limited influence of the low-temperature biochar on soil properties suggests the crucial importance of biochar-production technology and biochar properties on the effectiveness and validity of its application in agriculture.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 591
Author(s):  
Keke Song ◽  
Xiaoping Zou ◽  
Huiyin Zhang ◽  
Chunqian Zhang ◽  
Jin Cheng ◽  
...  

The electron transport layer (ETL) is critical to carrier extraction for perovskite solar cells (PSCs). Moreover, the morphology and surface condition of the ETL could influence the topography of the perovskite layer. ZnO, TiO2, and SnO2 were widely investigated as ETL materials. However, TiO2 requires a sintering process under high temperature and ZnO has the trouble of chemical instability. SnO2 possesses the advantages of low-temperature fabrication and high conductivity, which is critical to the performance of PSCs prepared under low temperature. Here, we optimized the morphology and property of SnO2 by modulating the concentration of a SnO2 colloidal dispersion solution. When adjusting the concentration of SnO2 colloidal dispersion solution to 5 wt.% (in water), SnO2 film indicated better performance and the perovskite film has a large grain size and smooth surface. Based on high efficiency (16.82%), the device keeps a low hysteresis index (0.23).


2017 ◽  
Vol 8 (5) ◽  
pp. 1701683 ◽  
Author(s):  
Randi Azmi ◽  
Wisnu Tantyo Hadmojo ◽  
Septy Sinaga ◽  
Chang-Lyoul Lee ◽  
Sung Cheol Yoon ◽  
...  

Author(s):  
L. S. Pioro ◽  
I. L. Pioro

It is well known that high-level radioactive wastes (HLRAW) are usually vitrified inside electric furnaces. Disadvantages of electric furnaces are their low melting capacity and restrictions on charge preparation. Therefore, a new concept for a high efficiency combined aggregate – submerged combustion melter (SCM)–electric furnace was developed for vitrification of HLRAW. The main idea of this concept is to use the SCM as the primary high-capacity melting unit with direct melt drainage into an electric furnace. The SCM employs a single-stage method for vitrification of HLRAW. The method includes concentration (evaporation), calcination, and vitrification of HLRAW in a single-stage process inside a melting chamber of the SCM. Specific to the melting process is the use of a gas-air or gas-oxygen-air mixture with direct combustion inside a melt. Located inside the melt are high-temperature zones with increased reactivity of the gas phase, the existence of a developed interface surface, and intensive mixing, leading to intensification of the charge melting and vitrification process. The electric furnace clarifies molten glass, thus preparing the high-quality melt for subsequent melt pouring into containers for final storage.


2018 ◽  
Vol 11 (03) ◽  
pp. 1850057 ◽  
Author(s):  
Reza Meshkini Far ◽  
Olena V. Ischenko ◽  
Alla G. Dyachenko ◽  
Oleksandr Bieda ◽  
Snezhana V. Gaidai ◽  
...  

Here, we report, for the first time, on the catalytic hydrogenation of CO2 to methane at atmospheric pressure. For the preparation of hydrogenation catalysts based on Ni and Fe metals, a convenient method is developed. According to this method, low-temperature reduction of the co-precipitated Ni and Fe oxides with hydrogen gives the effective and selective bimetallic Ni[Formula: see text]Fe[Formula: see text], Ni[Formula: see text]Fe[Formula: see text] and Ni[Formula: see text]Fe[Formula: see text] catalysts. At the temperature range of 300–400[Formula: see text]C, they exhibit a high efficiency of CH4 production with respect to monometallic Ni and Fe catalysts. The results imply a synergistic effect between Ni and Fe which caused the superior activity of the Ni[Formula: see text]Fe[Formula: see text] catalyst conversing [Formula: see text]% of CO2 into CH4 at 350[Formula: see text]C. To adapt the Ni–Fe catalysts in the industry, the effect of two different carriers on the efficiency of the alumina-supported Ni[Formula: see text]Fe[Formula: see text] catalyst was investigated. It is found that the Ni[Formula: see text]Fe[Formula: see text]/[Formula: see text]-Al2O3 catalyst effectively conversed CO2 giving 100% methane yield already at 275[Formula: see text]C.


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