Preparation of polypyrrole–polyurethane composite foam by vapor phase oxidative polymerization

1995 ◽  
Vol 55 (2) ◽  
pp. 283-287 ◽  
Author(s):  
Feifeng He ◽  
Mitsuru Omoto ◽  
Toshihiro Yamamoto ◽  
Hideo Kise
2013 ◽  
Vol 315 ◽  
pp. 872-878 ◽  
Author(s):  
S. Kanna Subramaniyan ◽  
Shahruddin Mahzan ◽  
Mohd Imran Ghazali ◽  
Ahmad Mujahid Ahmad Zaidi ◽  
Prasath Kesavan Prabagaran

Foam-filled enclosures are very common in structural crashworthiness to increase energy absorption. However, very less research has been targeted on potential use of natural/recycled material reinforced foam-filled tubes. Therefore, an experimental investigation was performed to quantify energy absorption capacity of polyurethane (PU) composite foam-filled circular steel tubes under quasi-static axial loading. The thickness of the tubes was varied from 1.9, 2.9 and 3.6 mm. The tubes were filled with PU composite foam. The PU composite foam was processed with addition of kenaf plant fiber and recycled rubber particles that were refined at 80 mesh particulates into PU system. The density of PU resin was varied from 100, 200 and 300 kgm-3. The PU composite foam-filled tubes were crushed axially at constant speed in a universal testing machine and their energy absorption was characterized from the resulting load-deflection data. Results indicate that PU composite foam-filled tubes exhibited better energy absorption capacity than those PU foam-filled tubes and its respective empty tubes. Interaction effect between the tube and the foam and incorporation of filler into PU system led to an increase in mean crushing load compared to that of the unfilled PU foam or tube itself. Relatively, progressively collapse modes were observed for all tested tubes. Findings suggested that composite foam-filled tubes could be used as crashworthy member.


2009 ◽  
Vol 87-88 ◽  
pp. 468-473 ◽  
Author(s):  
Xin Jin ◽  
Yong Yue Wang ◽  
Chang Fa Xiao

Polypyrrole/wool composite fiber was prepared by in situ oxidative polymerization from vapor phase and liquid phase pyrrole at room temperature, by using FeCl3 as catalyst. The effect of deposition technique on the surface morphology, mechanical properties and the electrical stability of fibers were discussed. The result showed that deposition technique has a strong effect and fiber prepared by vapor phase deposition has much fine and small granular structure, lower resistance, better mechanical property and electrical stability.


2014 ◽  
Vol 68 (3) ◽  
Author(s):  
Mohd Haziq Dzulkifli ◽  
Mohd Yazid Yahya ◽  
Farhana Shakira Md Akhir ◽  
Rohah Abd Majid

Polyurethane (PU) foams are widely used today in automotive and as insulation system. Due to environmental issues, efforts have been made to replace petrochemical polyol with natural-based polyol in PU foam production, without sacrificing any properties. This study aims as to produce palm oil-based polyurethane composite foam for load bearing purposes. Palm oil-based polyol (POP) was reacted with polymeric 4,4-diphenylmethane diisocyanate (p-MDI) with water as blowing agent and silicone surfactant to produce rigid PU foams. The foams obtained were varied by NCO:OH ratios and water content and characterized for their morphology and compressive strength. Scanning electron micrographs (SEM) indicated the cells within the obtained foams are closed cells. Compressive strength of obtained foams shows considerable improvement but only up to NCO:OH ratio of 1:1.35. 


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