Analysis and Comparison of Vapor and Liquid Deposition of Pyrrole on Wool Fiber

2009 ◽  
Vol 87-88 ◽  
pp. 468-473 ◽  
Author(s):  
Xin Jin ◽  
Yong Yue Wang ◽  
Chang Fa Xiao

Polypyrrole/wool composite fiber was prepared by in situ oxidative polymerization from vapor phase and liquid phase pyrrole at room temperature, by using FeCl3 as catalyst. The effect of deposition technique on the surface morphology, mechanical properties and the electrical stability of fibers were discussed. The result showed that deposition technique has a strong effect and fiber prepared by vapor phase deposition has much fine and small granular structure, lower resistance, better mechanical property and electrical stability.

2012 ◽  
Vol 476-478 ◽  
pp. 1374-1378
Author(s):  
Wen Yu Wang ◽  
Xin Jin ◽  
Yu Feng Zhang

The two deposition polymerization techniques, i.e. vapor phase and liquid phase pyrrole deposition polymerization were applied to Ultra-high-molecular-weight polyethylene (UHMWPE) fiber in this paper. The effect of deposition technique on the surface morphology, mechanical properties, electrical stability and surface roughness of fibers were discussed. The result showed that deposition technique has a strong effect on the properties of UHMWPE fibers. Fibers treated by vapor phase deposition polymerization has much fine and small granular structure, lower resistance, better mechanical property and higher surface roughness value.


2011 ◽  
Vol 221 ◽  
pp. 48-53 ◽  
Author(s):  
Jin Yun Xu ◽  
Xin Jin

Polyester fibers are used in a great many textile and industrial materials, their undesirable electrical advantage bring about disadvantages. Direct polymerization of pyrrole on polyester fibers may provide useful tools for producing new conducting materials. Polyester/polypyrrole composite fiber was prepared by in situ oxidative polymerization from liquid phase pyrrole at room temperature. The result showed that deposition of pyrrole is an effective way to impart conductivity to polyester fiber. The Tg of coated polyester fiber decreased and the surface of Ppy coated polyester fiber displayed an evident granular structure. In addition, the Ppy coatings have good stability under washing and heating treatment, which demonstrate that polypyrrole has good affinity to polyester fiber.


2009 ◽  
Vol 255 (15) ◽  
pp. 7012-7016 ◽  
Author(s):  
Araceli Rios Flores ◽  
R. Castro-Rodríguez ◽  
J.L. Peña ◽  
N. Romeo ◽  
A. Bosio

Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3077
Author(s):  
Rima D. Alharthy ◽  
Ahmed Saleh

In this study, we developed a new chemi-resistive, flexible and selective ammonia (NH3) gas sensor. The sensor was prepared by depositing thin film of polyaniline-cobalt ferrite (PAni-CoFe2O4) nanocomposite on flexible polyethylene terephthalate (PET) through an in situ chemical oxidative polymerization method. The prepared PAni-CoFe2O4 nanocomposite and flexible PET-PAni-CoFe2O4 sensor were evaluated for their thermal stability, surface morphology and materials composition. The response to NH3 gas of the developed sensor was examined thoroughly in the range of 1–50 ppm at room temperature. The sensor with 50 wt% CoFe2O4 NPs content showed an optimum selectivity to NH3 molecules, with a 118.3% response towards 50 ppm in 24.3 s response time. Furthermore, the sensor showed good reproducibility, ultra-low detection limit (25 ppb) and excellent flexibility. In addition, the relative humidity effect on the sensor performance was investigated. Consequently, the flexible PET-PAni-CoFe2O4 sensor is a promising candidate for trace-level on-site sensing of NH3 in wearable electronic or portable devices.


2014 ◽  
Vol 904 ◽  
pp. 159-163 ◽  
Author(s):  
Jia Ping Lao ◽  
Chao Yang ◽  
Hao Dao Mo ◽  
Yu Ping Li ◽  
Li Min Zang ◽  
...  

Functional floating bead (F-FB), prepared by anchoring the organic sulfonic acid on the surface of the blackberry-like structural FB, was used as both the inorganic substrate and the in situ dopant for the in situ chemical oxidative polymerization of pyrrole to obtain the plypyrrole/functional floating bead (PPy/F-FB) nanocomposite material. The composites possess high electrical conductivity at room temperature. Thermogravimetric analysis shows that the thermal stability of PPy/F-FB composites was enhanced and these can be attributed to the retardation effect of sulfonic acid-functionalized FB as barriers for the degradation of PPy. The morphology of PPy/FB composites showed the well-defined blackberry-like morphology.


2020 ◽  
Vol 12 (5) ◽  
pp. 5958-5967 ◽  
Author(s):  
Fang Li ◽  
Mohammad Rejaul Kaiser ◽  
Jianmin Ma ◽  
Yuyang Hou ◽  
Tengfei Zhou ◽  
...  

2018 ◽  
Vol 42 (9) ◽  
pp. 6918-6931 ◽  
Author(s):  
Madhurima Das ◽  
Saptarshi Ghosh ◽  
Somenath Roy

This article describes the non-covalent functionalization of multiwall carbon nanotubes (MWCNTs) with polycarbazole (PCz) via an in situ chemical oxidative polymerization method and subsequent fabrication of resistive humidity sensors.


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