Solubility and diffusivity measurements in nitrogen–poly(vinyl acetate) and nitrogen–toluene–poly(vinyl acetate) systems with the differential pressure decay technique

2008 ◽  
Vol 108 (3) ◽  
pp. 1407-1413 ◽  
Author(s):  
Reza Pourdarvish ◽  
Ronald P. Danner ◽  
J. Larry Duda
Vacuum ◽  
2019 ◽  
Vol 169 ◽  
pp. 108887
Author(s):  
Dexue You ◽  
Yongjian Wang ◽  
Zhenhua Yu ◽  
Yan Zhao ◽  
Zhenhua Xi ◽  
...  

Author(s):  
Heather A. Oravec ◽  
Christopher C. Daniels ◽  
Janice L. Mather

As deep space exploration continues to be the goal of NASA’s human spaceflight program, verification of the performance of spaceflight hardware becomes increasingly critical. Suitable test methods for verifying the leak rate of sealing systems are identified in program qualification testing requirements. One acceptable method for verifying the air leak rate of gas pressure seals is the tracer gas leak detector method. In this method, a tracer gas (commonly helium) leaks past the test seal and is transported to the leak detector where the leak rate is quantified. To predict the air leak rate, a conversion factor of helium-to-air is applied depending on the magnitude of the helium flow rate. The conversion factor is based on either the molecular mass ratio or the ratio of the dynamic viscosities. The current work was aimed at validating this approach for permeation-level leak rates using a series of tests with a silicone elastomer O-ring. An established pressure decay method with constant differential pressure was used to evaluate both the air and helium leak rates of the O-ring under similar temperature and pressure conditions. The results from the pressure decay tests showed, for the elastomer O-ring, that neither the molecular flow nor the viscous flow helium-to-air conversion factors were applicable. Leak rate tests were also performed using nitrogen and argon as the test gas. Molecular mass and viscosity based helium-to-test gas conversion factors were applied, but did not correctly predict the measured leak rates of either gas. To further this study, the effect of pressure boundary conditions was investigated. Often, pressure decay leak rate tests are performed at a differential pressure of 101.3 kPa with atmospheric pressure on the downstream side of the test seal. In space applications, the differential pressure is similar, but with vacuum as the downstream pressure. The same O-ring was tested at four unique differential pressures ranging from 34.5 to 137.9 kPa. Up to six combinations of upstream and downstream pressures for each differential pressure were compared. For a given differential pressure, the various combinations of upstream and downstream dry air pressures did not significantly affect the leak rate. As expected, the leak rate of the O-ring increased with increasing differential pressure. The results suggested that the current leak test pressure conditions, used to verify spacecraft sealing systems with elastomer seals, produce accurate values even though the boundary conditions do not model the space application.


2013 ◽  
Vol 819 ◽  
pp. 286-291
Author(s):  
Xin Hua Xiao ◽  
Tai Yong Wang ◽  
Bing Cheng

In auto leak detection equipment based on differential pressure decay, plugging quality directly impact on its accuracy and reliability. Since the cylinder is usually used to provide plugging force, plugging cylinder selection is an important part the detection equipment design. The main mechanical structure of the detection equipment was described. The equilibrium equations of plug were established and the bore size calculation formulas were derived in line seal and in face seal. To acquire the parameters such as circumference, area, etc. of the irregular seal surface, the subsection curve fitting-integration method and distilling from CAD model method were studied.


Author(s):  
M.A. Nisbet ◽  
S. Schmeller

AbstractBoth the vapour and particulate phases of tobacco smoke have been shown to retard benzoyI-peroxide-initiated polymerisation of vinyl acetate by interception of the radicals involved in the polymerisation process. The extent of inhibition of polymerisation by test compounds is estimated by measuring time taken for a mixture of monomer and benzoyl peroxide, immersed in a water-bath at 70°C, to reach a spontaneous boil and comparing it with the time required for a similar mixture with added retarder to reach boiling point. Units are expressed as minutes of inhibition per part per million of inhibitor × 10


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