Effect of reactive poly(ethylene glycol) flexible chains on curing kinetics and impact properties of bisphenol-a glycidyl ether epoxy

2011 ◽  
Vol 124 (3) ◽  
pp. 2325-2332 ◽  
Author(s):  
Dahu Yao ◽  
Tapas Kuila ◽  
Kyung-Bok Sun ◽  
Nam-Hoon Kim ◽  
Joong-Hee Lee
Keyword(s):  
Ethylene Glycol ◽  
Bisphenol A ◽  
Glycidyl Ether ◽  
Curing Kinetics ◽  
Poly Ethylene Glycol ◽  
Impact Properties ◽  
Poly Ethylene

Curing Kinetics and Rheology of Diglycidyiether of Bisphenol-A Modified by Poly(ethylene glycol) Flexible Chains

2010 ◽  
Vol 123-125 ◽  
pp. 411-414 ◽  
Author(s):  
Da Hu Yao ◽  
Kyung Bok Sun ◽  
Peng Li ◽  
Joong Hee Lee
Keyword(s):  
Ethylene Glycol ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Kinetic Parameters ◽  
Curing Kinetics ◽  
Poly Ethylene Glycol ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Curing Reaction ◽  
Poly Ethylene

The curing reaction of the system bisphenol-A glycidol ether epoxy resin modified by poly (ethylene glycol) (PEO) and flexible amine (D-230) as curing agent has been studied by means of differential scanning calorimetry (DSC) and thermal scanning rheometry. The curing kinetic parameters have been calculated from the non-thermal DSC curve. The kinetic analysis suggests that the two-parameter autocatalytic model is more appropriate to describe the kinetics of the curing reaction of the system. Increasing the PU content leads to an increase in the heat of curing and has a little effect on the kinetic parameters apparent activation energy (Ea), pre-exponential factor (A), and order of the reaction (m and n). The rheological properties were measured by isothermal curing evolution. Introduction of PEO flexible chains delayed the polymerization. It has been confirmed that the introduction of PEO chains in the structure of the epoxy resin increases the mobility of the molecular segment of the epoxy networks and results in the decrease in glass transition temperature.

scholarly journals Evaluation of the Ultraviolet-Curing Kinetics of Ultraviolet-Polymerized Oligomers Cured Using Poly (Ethylene Glycol) Dimethacrylate

Coatings ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 99 ◽  
Author(s):  
Ji-Won Park ◽  
Jong-Gyu Lee ◽  
Gyu-Seong Shim ◽  
Hyun-Joong Kim ◽  
Young-Kwan Kim ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Curing Kinetics ◽  
Ethylene Glycol Dimethacrylate ◽  
Glycol Dimethacrylate ◽  
Poly Ethylene Glycol ◽  
Ultraviolet Curing ◽  
Poly Ethylene ◽  
Kinetics Of

Hydrogels with multiple clickable anchor points: synthesis and characterization of poly(furfuryl glycidyl ether)-block-poly(ethylene glycol) macromonomers

2019 ◽  
Vol 10 (32) ◽  
pp. 4485-4494 ◽  
Author(s):  
Karishma K. Adatia ◽  
Silke Keller ◽  
Tobias Götz ◽  
Günter E. M. Tovar ◽  
Alexander Southan
Keyword(s):  
Ethylene Glycol ◽  
Glycidyl Ether ◽  
Diels Alder ◽  
Synthesis And Characterization ◽  
Poly Ethylene Glycol ◽  
Polyacrylamide Hydrogels ◽  
Anchor Points ◽  
Poly Ethylene

Functional polyacrylamide hydrogels containing multiple furfuryl anchor points for Diels–Alder reactions were prepared employing new macromonomers.

Composite proton-conducting membranes based on poly(ethylene glycol vinyl glycidyl ether)

2014 ◽  
Vol 56 (2) ◽  
pp. 229-237 ◽  
Author(s):  
M. V. Markova ◽  
D. M. Mognonov ◽  
L. V. Morozova ◽  
A. I. Mikhaleva ◽  
B. A. Trofimov
Keyword(s):  
Ethylene Glycol ◽  
Glycidyl Ether ◽  
Poly Ethylene Glycol ◽  
Proton Conducting ◽  
Poly Ethylene ◽  
Conducting Membranes

Nano-capsules of amphiphilic poly(ethylene glycol)-block-poly(bisphenol A carbonate) copolymers via thermodynamic entrapment

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6065-6071 ◽  
Author(s):  
A. Sutti ◽  
T. Chaffraix ◽  
A. S. Voda ◽  
A. Taylor ◽  
K. Magniez
Keyword(s):  
Ethylene Glycol ◽  
Bisphenol A ◽  
Poly Ethylene Glycol ◽  
Water Addition ◽  
Simple Preparation ◽  
Poly Ethylene

Fast and simple preparation of nano-capsules by water addition to poly(ethylene glycol)-block-poly(bisphenol A carbonate) copolymers in THF.

scholarly journals Oxidation-Responsive and “Clickable” Poly(ethylene glycol) via Copolymerization of 2-(Methylthio)ethyl Glycidyl Ether

2016 ◽  
Vol 138 (29) ◽  
pp. 9212-9223 ◽  
Author(s):  
Jana Herzberger ◽  
Karl Fischer ◽  
Daniel Leibig ◽  
Matthias Bros ◽  
Raphael Thiermann ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Glycidyl Ether ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

Synthesis and sequence-controlled self-assembly of amphiphilic triblock copolymers based on functional poly(ethylene glycol)

2017 ◽  
Vol 8 (45) ◽  
pp. 6964-6971 ◽  
Author(s):  
Yanxin Qi ◽  
Bin Li ◽  
Yupeng Wang ◽  
Yubin Huang
Keyword(s):  
Ethylene Glycol ◽  
Self Assembly ◽  
Ring Opening ◽  
Glycidyl Ether ◽  
Ring Opening Polymerization ◽  
Poly Ethylene Glycol ◽  
Amphiphilic Triblock Copolymer ◽  
Allyl Glycidyl Ether ◽  
Poly Ethylene ◽  
Copolymer Poly

Given the increasing prosperity of multifunctional poly(ethylene glycol) (mf-PEG), an amphiphilic triblock copolymer, poly(ethylene glycol)-block-poly(ε-caprolactone)-block-poly(allyl glycidyl ether) (mPEG-PCL-PAGE), was synthesized by a combination of living ring-opening polymerization (ROP) and click chemistry.

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