Hierarchical Self-Assembly of Supramolecular Hydrophobic Metallacycles into Ordered Nanostructures

2014 ◽  
Vol 9 (10) ◽  
pp. 2928-2936 ◽  
Author(s):  
Jing Zhang ◽  
Riccardo Marega ◽  
Li-Jun Chen ◽  
Nai-Wei Wu ◽  
Xing-Dong Xu ◽  
...  
Nano LIFE ◽  
2016 ◽  
Vol 06 (03n04) ◽  
pp. 1642007
Author(s):  
Zhili Yao ◽  
Yuan Sun ◽  
Chen Kang

The one-dimensional (1D) self-assembly of [Formula: see text]-electron molecules offers efficient strategies to enhance energy and charge transfer via highly ordered and conductive [Formula: see text] stacking of the chromophores. The chromophore rich nanostructures have great potential to serve as promising candidate materials for optoelectronic devices. However, the design and control of highly ordered nanostructures with multicolored chromophore redox gradients require finely chosen synthetic strategies and a delicate balance of supramolecular interactions. In this paper, we will introduce new strategies focused on self-assembly of nanofibers based on lysine derivatives functionalized with multi colored chromophores.


2018 ◽  
Vol 87 (1) ◽  
pp. 533-553 ◽  
Author(s):  
Ehud Gazit

The formation of ordered nanostructures by molecular self-assembly of proteins and peptides represents one of the principal directions in nanotechnology. Indeed, polyamides provide superior features as materials with diverse physical properties. A reductionist approach allowed the identification of extremely short peptide sequences, as short as dipeptides, which could form well-ordered amyloid-like β-sheet-rich assemblies comparable to supramolecular structures made of much larger proteins. Some of the peptide assemblies show remarkable mechanical, optical, and electrical characteristics. Another direction of reductionism utilized a natural noncoded amino acid, α-aminoisobutryic acid, to form short superhelical assemblies. The use of this exceptional helix inducer motif allowed the fabrication of single heptad repeats used in various biointerfaces, including their use as surfactants and DNA-binding agents. Two additional directions of the reductionist approach include the use of peptide nucleic acids (PNAs) and coassembly techniques. The diversified accomplishments of the reductionist approach, as well as the exciting future advances it bears, are discussed.


2014 ◽  
Vol 53 (1) ◽  
pp. 85-92 ◽  
Author(s):  
Zhuoshi Wang ◽  
Keli Zhong ◽  
Yongri Liang ◽  
Tie Chen ◽  
Bingzhu Yin ◽  
...  

2020 ◽  
Vol 6 (31) ◽  
pp. eabb6462
Author(s):  
Tae Wan Park ◽  
Myunghwan Byun ◽  
Hyunsung Jung ◽  
Gyu Rac Lee ◽  
Jae Hong Park ◽  
...  

Nanotransfer printing (nTP) has attracted considerable attention due to its good pattern resolution, process simplicity, and cost-effectiveness. However, the development of a large-area nTP process has been hampered by critical reliability issues related to the uniform replication and regular transfer printing of functional nanomaterials. Here, we present a very practical thermally assisted nanotransfer printing (T-nTP) process that can easily produce well-ordered nanostructures on an 8-inch wafer via the use of a heat-rolling press system that provides both uniform pressure and heat. We also demonstrate various complex pattern geometries, such as wave, square, nut, zigzag, and elliptical nanostructures, on diverse substrates via T-nTP. Furthermore, we demonstrate how to obtain a high-density crossbar metal-insulator-metal memristive array using a combined method of T-nTP and directed self-assembly. We expect that the state-of-the-art T-nTP process presented here combined with other emerging patterning techniques will be especially useful for the large-area nanofabrication of various devices.


2021 ◽  
Author(s):  
Hua-Feng Fei ◽  
Benjamin M. Yavitt ◽  
Sravya Nuguri ◽  
Yong-Guen Yu ◽  
James J. Watkins

RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 50091-50096 ◽  
Author(s):  
Young-Kwan Kim ◽  
Hee-Kyung Na ◽  
Seulbeom Ham ◽  
Dal-Hee Min

The evaporation induced self-assembly of nanomaterials has emerged as one of the important approaches to fabricate various ordered nanostructures with enhanced optical properties.


2015 ◽  
Vol 3 (22) ◽  
pp. 11688-11699 ◽  
Author(s):  
Qiannan Liu ◽  
Ziqi Sun ◽  
Yuhai Dou ◽  
Jung Ho Kim ◽  
Shi Xue Dou

In this highlight, we proposed the concept of two-step self-assembly approach for the synthesis of hierarchically-ordered multifunctional nanostructures.


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