Rhodium Single‐Atom Catalysts on Titania for Reverse Water Gas Shift Reaction Explored by First Principles Mechanistic Analysis and Compared to Nanoclusters

ChemCatChem ◽  
2021 ◽  
Author(s):  
Francis Doherty ◽  
Bryan R. Goldsmith
Keyword(s):  
First Principles ◽  
Water Gas Shift ◽  
Single Atom ◽  
Water Gas Shift Reaction ◽  
Reverse Water Gas Shift ◽  
Mechanistic Analysis ◽  
Shift Reaction ◽  
Water Gas

Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

2021 ◽  
Author(s):  
Daiya Kobayashi ◽  
Hirokazu Kobayashi ◽  
Kohei Kusada ◽  
Tomokazu Yamamoto ◽  
Takaaki Toriyama ◽  
...  
Keyword(s):  
Pt Nanoparticles ◽  
Water Gas Shift ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Water Gas Shift Reaction ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas ◽  
First Time

We report PtW solid-solution alloy nanoparticles (NPs) as a reverse water-gas shift (RWGS) reaction catalyst for the first time. Atomic-level alloying of Pt and W significantly enhanced the RWGS reaction activity of Pt NPs.

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