ChemInform Abstract: 2H,8H-5-OXO-5-METHYL(PHENYL)DIBENZO(C,F)-1,5-OXA-, THIA-, AND AZAPHOSPHOCINES - NEW PHOSPHORUS-CONTAINING HETEROCYCLES

1979 ◽  
Vol 10 (6) ◽  
Author(s):  
K. A. PETROV ◽  
V. A. CHAUZOV ◽  
N. YU. LEVEDEVA ◽  
L. P. CHERNOBROVKINA
2003 ◽  
Vol 769 ◽  
Author(s):  
Asha Sharma ◽  
Deepak ◽  
Monica Katiyar ◽  
Satyendra Kumar ◽  
V. Chandrasekhar ◽  
...  

AbstractThe optical degradation of polysilane copolymer has been studied in spin cast thin films and solutions using light source of 325 nm wavelength. The room temperature photoluminescence (PL) spectrum of these films show a sharp emission at 368 nm when excited with a source of 325 nm. However, the PL intensity deteriorates with time upon light exposure. Further the causes of this degradation have been examined by characterizing the material for its transmission behaviour and changes occurring in molecular weight as analysed by GPC data.


2020 ◽  
Vol 2020 (9) ◽  
pp. 13-17
Author(s):  
Yuriy Ryzhov ◽  
Svetlana Abramova

There is carried out a number of experiments with the purpose of analyzing SOTS impact upon both finishing productivity, and physical-chemical state and tribological behavior of surfaces machined, and also a possibility for creation according to the results of the investigations carried out a relatively universal micro-emulsion SOTS based on existing in the Ukraine the line of oils, PAV, corrosion inhibitors, alloying additives etc. As SOTS samples there were used both well-known compouds, for example, Camix, Nope Right (USA), and carbamide having in its structure boron, boron-phosphorus-containing additive, water-solvable phosphate, tributyl phosphate (oil-solvable), concentrate SOTS tribol, having in its structure compounds of boron, nitrogen and phosphorous; ethylic ether of fatty acids; methyl ether of colza oil; Sarkozyl-O having in its structure easily-decomposable chlorine compounds. From the results obtained it is possible to draw a conclusion that during finishing in the environment of water-compatible SOTS an important role in the formation of the properties of the surface worked is played by hydrocarbon components and additives which contribute to the formation of the thinnest surface layers modified with carbon and oxygen.


2012 ◽  
Vol 19 (29) ◽  
pp. 5044-5051 ◽  
Author(s):  
V. Briz ◽  
M.J. Serramia ◽  
R. Madrid ◽  
A. Hameau ◽  
Anne-Marie Caminade ◽  
...  

1988 ◽  
Vol 53 (11) ◽  
pp. 2503-2510 ◽  
Author(s):  
Jef J. M. Sleeckx ◽  
Marc J. O. Anteunis ◽  
Frans A. M. Borremans

The conformational behaviour of a series of N-substituted thiohydantoins of proline was studied by proton NMR. The pseudorotational parameters of the proline moiety were calculated from the ten vicinal proton-proton coupling constants assuming a two state equilibrium (N ⇋ S). The effect of the different substituents (methyl, phenyl, para-nitrophenyl) at the thiohydantoin nitrogen on the conformation of the pyrrolidine rings is discussed. The spectra of proline-N-methylthiohydantoin were recorded at different temperatures in octadeuterotoluene solution. The conformational analysis of these spectra showed that the ratio of the populations of the N and S forms changes considerably with temperature, while the conformational identity of both the N and S forms remains strictly preserved. These facts provide an additional experimental justification of the two-state assumption, at least so for the present model compounds.


Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.


2017 ◽  
Vol 41 ◽  
pp. 630-647 ◽  
Author(s):  
Mahir Burak SÜDEMEN ◽  
Hacer Ayşen ÖNEN

1978 ◽  
Vol 9 (44) ◽  
Author(s):  
V. P. LYSENKO ◽  
I. E. BOLDESKUL ◽  
R. A. LOKTIONOVA ◽  
YU. G. GOLOLOBOV

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