ChemInform Abstract: Crystal Structure of Silica-ZSM-12 by the Combined Use of High-Resolution Solid-State MAS NMR Spectroscopy and Synchrotron X-Ray Powder Diffraction.

ChemInform ◽  
1990 ◽  
Vol 21 (31) ◽  
Author(s):  
C. A. FYFE ◽  
H. GIES ◽  
G. T. KOKOTAILO ◽  
B. MARLER ◽  
D. E. COX
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
High Resolution ◽  
Powder Diffraction ◽  
Mas Nmr ◽  
X Ray ◽  
Combined Use

scholarly journals Synthesis, characterization and modeling of self-assembled porphyrin nanorods

2019 ◽  
Vol 23 (11n12) ◽  
pp. 1346-1354 ◽  
Author(s):  
Danielle Laurencin ◽  
Pascal G. Yot ◽  
Christel Gervais ◽  
Yannick Guari ◽  
Sébastien Clément ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Dft Calculations ◽  
Powder Diffraction ◽  
Solid State Nmr ◽  
Molecular Level ◽  
Ion Association ◽  
Free Base ◽  
X Ray ◽  
Solid State Nmr Spectroscopy

Porphyrin nanorods were prepared by ion-association between free-base meso 5,10,15,20-tetrakis-(4-[Formula: see text]-methylpyridinium)porphyrin cations and tetraphenylborate anions. The nanorods have variable lengths (up to a few micrometers long) and diameters ([Formula: see text]50–500 nm). Their structure at the molecular level was elucidated by combining multinuclear solid state NMR spectroscopy, synchrotron X-ray powder diffraction and DFT calculations.

scholarly journals Crystal structure and tautomerism of Pigment Yellow 138 determined by X-ray powder diffraction and solid-state NMR

2016 ◽  
Vol 131 ◽  
pp. 364-372 ◽  
Author(s):  
Silke D. Gumbert ◽  
Meike Körbitzer ◽  
Edith Alig ◽  
Martin U. Schmidt ◽  
Michele R. Chierotti ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Powder Diffraction ◽  
Solid State Nmr ◽  
X Ray

SYNTHESIS, MORPHOLOGY AND STRUCTURAL PROPERTIES OF (GD,ND)SR2RUCU2O8 SAMPLES

2003 ◽  
Vol 17 (04n06) ◽  
pp. 899-904 ◽  
Author(s):  
A. VECCHIONE ◽  
M. GOMBOS ◽  
C. TEDESCO ◽  
A. IMMIRZI ◽  
L. MARCHESE ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Solid State ◽  
Powder Diffraction ◽  
Solid State Reaction ◽  
X Ray ◽  
Structure And Morphology ◽  
Polycrystalline Powder ◽  
Scanning Electron

NdSr 2 RuCu 2 O x material has been prepared as polycrystalline powder by solid state reaction. The compound has been investigated by synchrotron x-ray powder diffraction and scanning electron microscopy. The experimental results show that the average crystal structure is a disordered cubic perovskite with Nd and Sr cations occupying the same site and the same substitution is found for Cu and Ru atoms. A comparison between the crystal structure and morphology of this compound and the superconducting tetragonal GdSr 2 RuCu 2 O 8 is also discussed.

Crystal structure study of selected xanthine derivatives

2010 ◽  
Vol 43 (1) ◽  
pp. 163-167 ◽  
Author(s):  
W. Lasocha ◽  
B. Gaweł ◽  
A. Rafalska-Lasocha ◽  
M. Pawłowski ◽  
P. Talik ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Resolution ◽  
Powder Diffraction ◽  
Structure Study ◽  
Asymmetric Unit ◽  
Pharmaceutical Samples ◽  
X Ray ◽  
Xanthine Derivatives ◽  
Structure Solution ◽  
Theophylline Derivatives

The crystal structures of two compounds belonging to a group of theophylline derivatives have been solved by X-ray powder diffraction methods. Despite the fact that these compounds seemed to be rather simple (23 atoms in an asymmetric unit), the preferred orientation and dominant zone problems created very serious obstacles in the investigations, even for the most modern powder diffraction methods. The crystal structure of the first compound, 8-phenylazoxanthine, C14H14N6O2, was finally solved from laboratory diffractometer data, while in the case of the second compound, 8-(3-bromobenzylidene)xanthine, C15H14N5O2Br, it was not possible to reliably index its diffraction pattern until data had been collected at the high-resolution powder diffractometer ID31 at the ESRF Grenoble. The serious problems encountered during anab initiocrystal structure solution from powder data of these pharmaceutical samples are described and discussed.

scholarly journals Hydrate of 2,3:4,5-di-O-isopropylidene-β-D-arabino-hexos-2-ulo-2,6-pyranose as new crystalline reagent in the preparation of Amadori derived peptides

2010 ◽  
Vol 8 (1) ◽  
pp. 28-33 ◽  
Author(s):  
Piotr Stefanowicz ◽  
Joanna Batorska ◽  
Monika Kijewska ◽  
Hubert Bartosz-Bechowski ◽  
Zbigniew Szewczuk ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Nmr Spectroscopy ◽  
High Resolution ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Crystalline Hydrate ◽  
Phase Synthesis ◽  
X Ray ◽  
Independent Molecules ◽  
Stable Reagent

AbstractWe established, that crystalline hydrate of 2,3:4,5-di-O-isopropylidene-β-D-arabino-hexos-2-ulo-2,6-pyranose is a new, convenient and stable reagent for solid phase synthesis of peptide derived Amadori products. The structure of the title compound was studied by X-ray analysis, NMR spectroscopy, and high resolution ESI-MS. The crystal structure indicated the existence of two symmetry-independent molecules that were not connected with hydrogen bonds. A comparison with previously reported 2,3:4,5-di-O-isopropylidene-β-D-fructopyranose revealed, that these two compounds are isostructural.

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