Synthesis, characterization and modeling of self-assembled porphyrin nanorods

Porphyrin nanorods were prepared by ion-association between free-base meso 5,10,15,20-tetrakis-(4-[Formula: see text]-methylpyridinium)porphyrin cations and tetraphenylborate anions. The nanorods have variable lengths (up to a few micrometers long) and diameters ([Formula: see text]50–500 nm). Their structure at the molecular level was elucidated by combining multinuclear solid state NMR spectroscopy, synchrotron X-ray powder diffraction and DFT calculations.

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Molecular-level environments of intercalated chloroaluminate anions in rechargeable aluminum-graphite batteries revealed by solid-state NMR spectroscopy

Journal of Materials Chemistry A ◽

10.1039/d0ta02611e ◽

2020 ◽

Vol 8 (31) ◽

pp. 16006-16017

Author(s):

Jeffrey H. Xu ◽

Ankur L. Jadhav ◽

Damon E. Turney ◽

Robert J. Messinger

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Dft Calculations ◽

Solid State Nmr ◽

Molecular Level ◽

Mas Nmr ◽

Graphite Electrodes ◽

Solid State Nmr Spectroscopy ◽

Intercalated Graphite ◽

Wide Range

Solid-state 27Al MAS NMR spectroscopy and DFT calculations reveal that intercalated AlCl4− anions exhibit a wide range of molecular geometries and environments, establishing that the intercalated graphite electrodes exhibit high extents of disorder.

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Probing the role of ceramide hydroxylation in skin barrier lipid models by 2H solid-state NMR spectroscopy and X-ray powder diffraction

Biochimica et Biophysica Acta (BBA) - Biomembranes ◽

10.1016/j.bbamem.2018.02.003 ◽

2018 ◽

Vol 1860 (5) ◽

pp. 1162-1170 ◽

Cited By ~ 5

Author(s):

Andrej Kováčik ◽

Alexander Vogel ◽

Juliane Adler ◽

Petra Pullmannová ◽

Kateřina Vávrová ◽

...

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Powder Diffraction ◽

Solid State Nmr ◽

Skin Barrier ◽

X Ray ◽

Solid State Nmr Spectroscopy

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Structure Elucidation of a Novel Aluminum Methylphosphonate, Al3(CH3PO3)2·O·(OH)3, through a Combination of X-ray Powder Diffraction, Solid-State NMR Spectroscopy, and Computational Energy Minimization

Chemistry of Materials ◽

10.1021/cm011296q ◽

2002 ◽

Vol 14 (8) ◽

pp. 3432-3439 ◽

Cited By ~ 6

Author(s):

Mark Edgar ◽

Vinton J. Carter ◽

Paramjit Grewal ◽

Lesley-J. Sawers ◽

Enrique Sastre ◽

...

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Powder Diffraction ◽

Energy Minimization ◽

Solid State Nmr ◽

Structure Elucidation ◽

X Ray ◽

Solid State Nmr Spectroscopy

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Apatite Crystallization in an Aluminosilicate Glass Matrix: Mechanistic Studies by X-ray Powder Diffraction, Thermal Analysis, and Multinuclear Solid-State NMR Spectroscopy

Chemistry of Materials ◽

10.1021/cm0101834 ◽

2001 ◽

Vol 13 (11) ◽

pp. 4198-4206 ◽

Cited By ~ 16

Author(s):

Jerry C. C. Chan ◽

Richard Ohnsorge ◽

Karin Meise-Gresch ◽

Hellmut Eckert ◽

Wolfram Höland ◽

...

Keyword(s):

Thermal Analysis ◽

Solid State ◽

Nmr Spectroscopy ◽

Powder Diffraction ◽

Solid State Nmr ◽

Glass Matrix ◽

Aluminosilicate Glass ◽

Mechanistic Studies ◽

X Ray ◽

Solid State Nmr Spectroscopy

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Structure of Tetrakis(melaminium) Bis(dihydrogenphosphate) Monohydrogenphosphate Trihydrate from X-ray Powder Diffraction and Solid-State NMR Spectroscopy

The Journal of Physical Chemistry C ◽

10.1021/jp801985h ◽

2008 ◽

Vol 112 (32) ◽

pp. 12515-12523 ◽

Cited By ~ 6

Author(s):

Vladimir Brodski ◽

René Peschar ◽

Henk Schenk ◽

Andreas Brinkmann ◽

Ernst R. H. van Eck ◽

...

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Powder Diffraction ◽

Solid State Nmr ◽

X Ray ◽

Solid State Nmr Spectroscopy

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Investigation of structural and dynamic properties of NH4[N(CN)2] by means of X-ray and neutron powder diffraction as well as vibrational and solid-state NMR spectroscopy

Journal of Solid State Chemistry ◽

10.1016/s0022-4596(03)00388-8 ◽

2003 ◽

Vol 176 (1) ◽

pp. 180-191 ◽

Cited By ~ 19

Author(s):

Bettina V. Lotsch ◽

Jürgen Senker ◽

Winfried Kockelmann ◽

Wolfgang Schnick

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Powder Diffraction ◽

Solid State Nmr ◽

Dynamic Properties ◽

Neutron Powder Diffraction ◽

X Ray ◽

Solid State Nmr Spectroscopy

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A New Methodological Approach to Correlate Protective and Microscopic Properties by Soft X-ray Microscopy and Solid State NMR Spectroscopy: The Case of Cusa’s Stone

Applied Sciences ◽

10.3390/app11135767 ◽

2021 ◽

Vol 11 (13) ◽

pp. 5767

Author(s):

Veronica Ciaramitaro ◽

Alberto Spinella ◽

Francesco Armetta ◽

Roberto Scaffaro ◽

Emmanuel Fortunato Gulino ◽

...

Keyword(s):

Solid State ◽

Nmr Spectroscopy ◽

Solid State Nmr ◽

Methodological Approach ◽

Polymer Chains ◽

General Question ◽

Protective Agent ◽

Vapour Permeability ◽

X Ray ◽

Solid State Nmr Spectroscopy

Hydrophobic treatment is one of the most important interventions usually carried out for the conservation of stone artefacts and monuments. The study here reported aims to answer a general question about how two polymers confer different protective performance. Two fluorinated-based polymer formulates applied on samples of Cusa’s stone confer a different level of water repellence and water vapour permeability. The observed protection action is here explained on the basis of chemico-physical interactions. The distribution of the polymer in the pore network was investigated using scanning electron microscopy and X-ray microscopy. The interactions between the stone substrate and the protective agents were investigated by means of solid state NMR spectroscopy. The ss-NMR findings reveal no significant changes in the chemical neighbourhood of the observed nuclei of each protective agent when applied onto the stone surface and provide information on the changes in the organization and dynamics of the studied systems, as well as on the mobility of polymer chains. This allowed us to explain the different macroscopic behaviours provided by each protective agent to the stone substrate.

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