ChemInform Abstract: Quaternary Chalcogenides Containing a Rare Earth and an Alkali- or Alkaline-Earth Metal

ChemInform ◽  
2010 ◽  
Vol 27 (6) ◽  
pp. no-no
Author(s):  
P. WU ◽  
J. A. IBERS
2021 ◽  
Author(s):  
Kota Matsumoto ◽  
Hideyuki Kawasoko ◽  
Noriaki Kimura ◽  
Tomoteru Fukumura

Metallic anti-ThCr2Si2-type RE2O2Bi (RE = rare earth) with Bi square nets show superconductivity while insulating La2O2Bi shows high hole mobility, by expanding the c-axis length through oxygen intercalation. In this...


2011 ◽  
Vol 694 ◽  
pp. 613-615
Author(s):  
Jun Zhang ◽  
Xiao Ting Shi ◽  
Wei Guo ◽  
Zhong Zhang ◽  
Hong Yang

The structural transition of DNA double-stranded induced by Ce3+ or Mg2+ ions was investigated in this paper. By atomic force microscopy, different types of condensed DNA structures were observed at the presence of Ce3+ or Mg2+ ions. The results show that there are some differences between rare earth ions and alkaline earth metal ions in the DNA condensation process.


1995 ◽  
Vol 42 (11) ◽  
pp. 1333-1337
Author(s):  
Shigeru Katsuyama ◽  
Yoshiyuki Tanaka ◽  
Yoichi Shichijo ◽  
Kazuhiko Majima ◽  
Hiroshi Nagai

Author(s):  
Igor Oshchapovsky ◽  
Volodymyr Pavlyuk ◽  
Grygoriy Dmytriv ◽  
Alexandra Griffin

The structure of lanthanum tetrazinc, LaZn4, has been determined from single-crystal X-ray diffraction data for the first time, approximately 70 years after its discovery. The compound exhibits a new structure type in the space groupCmcm, with one La atom and two Zn atoms occupying sites withm2msymmetry, and one Zn atom occupying a site with 2.. symmetry. The structure is closely related to the BaAl4, La3Al11, BaNi2Si2and CaCu5structure types, which can be presented as close-packed arrangements of 18-vertex clusters, in this case LaZn18. The kindred structure types contain related 18-vertex clusters around atoms of the rare earth or alkaline earth metal.


2019 ◽  
Vol 234 (3) ◽  
pp. 201-209 ◽  
Author(s):  
Dominik Stoiber ◽  
Rainer Niewa

Abstract A new simple approach to quantitative measures of coordination polyhedra distortions from ideal symmetry is provided with PolyDis. Within the mathematical basis, it minimizes the normalized displacements of given polyhedra to the ideal shape. Applications are discussed, where PolyDis was used to analyze the temperature dependent distortion of LaAlO3, rare earth metal radius dependent distortion of RMnO3 and the increasing structural distortion of (A3N)As with varying alkaline earth metal, all being perovskites. Additionally, the more complex structures of SrCuRSe3 and CsCu3R2Se5 comprising trigonal prisms, octahedra and tetrahedra are treated with PolyDis.


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