Photooxidation of IR ‐820 by Calixpyridinium‐Induced Assembled Material and Its pH‐Controlled Visual Multicolor Luminescence

Author(s):  
Kui Wang ◽  
Guo‐Jie Gao ◽  
Xiao‐Yan Wang
Keyword(s):  
Author(s):  
Luke Power ◽  
Adam D. Clayton ◽  
William Reynolds ◽  
David Hose ◽  
Caroline Ainsworth ◽  
...  

We present a rapid continuous processing methodology to screen for the optimal, selective, liquid-liquid extraction conditions, from a typical post-reaction mixture of amines, using both inline and online analysis to...


2002 ◽  
Vol 41 (18) ◽  
pp. 4612-4614 ◽  
Author(s):  
Luigi Fabbrizzi ◽  
Francesco Foti ◽  
Maurizio Licchelli ◽  
Antonio Poggi

2006 ◽  
Vol 39 ◽  
pp. S307
Author(s):  
C.-F. Koening ◽  
M. Krings ◽  
D. Mavrilas ◽  
B. Glasmacher

2017 ◽  
Vol 95 (9) ◽  
pp. 991-998 ◽  
Author(s):  
Prabal K. Maiti

Using fully atomistic molecular dynamics simulation that are several hundred nanoseconds long, we demonstrate the pH-controlled sponge action of PAMAM dendrimer. We show how at varying pH levels, the PAMAM dendrimer acts as a wet sponge; at neutral or low pH levels, the dendrimer expands noticeably and the interior of the dendrimer opens up to host several hundreds to thousands of water molecules depending on the generation number. Increasing the pH (i.e., going from low pH to high pH) leads to the collapse of the dendrimer size, thereby expelling the inner water, which mimics the ‘sponge’ action. As the dendrimer size swells up at a neutral pH or low pH due to the electrostatic repulsion between the primary and tertiary amines that are protonated at this pH, there is dramatic increase in the available solvent accessible surface area (SASA), as well as solvent accessible volume (SAV).


Sign in / Sign up

Export Citation Format

Share Document