Bagasse‐derived Carbon‐supported Ru nanoparticles as Catalyst for Efficient Dehydrogenation of Ammonia Borane

ChemNanoMat ◽  
2020 ◽  
Vol 6 (8) ◽  
pp. 1251-1259 ◽  
Author(s):  
Wei Cheng ◽  
Xue Zhao ◽  
Wenxiu Luo ◽  
Yun Zhang ◽  
Yi Wang ◽  
...  
2014 ◽  
Vol 257 ◽  
pp. 293-299 ◽  
Author(s):  
Qilu Yao ◽  
Weimei Shi ◽  
Gang Feng ◽  
Zhang-Hui Lu ◽  
Xiaoliang Zhang ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 267 ◽  
Author(s):  
Juti Rani Deka ◽  
Diganta Saikia ◽  
Kuo-Shu Hsia ◽  
Hsien-Ming Kao ◽  
Yung-Chin Yang ◽  
...  

Cubic mesoporous silica SBA-1 functionalized with carboxylic acid (-COOH), namely S1B-C10, is used as a support to fabricate and confine Ru nanoparticles (NPs). The uniformly dispersed organic functional groups in SBA-1 are beneficial in attracting Ru cations, and as a result, homogenously distributed small sized Ru NPs are formed within the mesopores. The prepared Ru@S1B-C10 is utilized as a catalyst for H2 generation from the hydrolysis of ammonia borane (AB). The Ru@S1B-C10 catalyst demonstrates high catalytic activity for H2 generation (202 mol H2 molRu min−1) and lower activation energy (24.13 kJ mol−1) due to the small sized Ru NPs with high dispersion and the support’s interconnected mesoporous structure. The nanosized Ru particles provide abundant active sites for the catalytic reaction to take place, while the interconnected porous support facilitates homogenous transference and easy dispersal of AB molecules to the active sites. The catalyst demonstrates good recycle ability since the accumulation and leaking of NPs throughout catalysis can be effectively prevented by the support.


2016 ◽  
Vol 41 (15) ◽  
pp. 6300-6309 ◽  
Author(s):  
Kunzhou Yang ◽  
Liqun Zhou ◽  
Guofeng Yu ◽  
Xing Xiong ◽  
Menglin Ye ◽  
...  

2019 ◽  
Vol 43 (11) ◽  
pp. 4377-4384 ◽  
Author(s):  
Zhenkai Cui ◽  
Yueping Guo ◽  
Zhishang Feng ◽  
Dan Xu ◽  
Jiantai Ma

The two-dimensional magnetic NC-Fe materials were prepared and modified with Ru nanoparticles to form Ru/NC-Fe nanocatalyst with excellent catalytic activity for hydrogen evolution from ammonia borane.


2016 ◽  
Vol 41 (3) ◽  
pp. 1542-1549 ◽  
Author(s):  
Guangyin Fan ◽  
Qingqing Liu ◽  
Daomei Tang ◽  
Xiaojing Li ◽  
Jian Bi ◽  
...  

2020 ◽  
Vol 595 ◽  
pp. 117511 ◽  
Author(s):  
Yong-Ting Li ◽  
Shi-Hao Zhang ◽  
Guang-Ping Zheng ◽  
Pu Liu ◽  
Zhi-Kun Peng ◽  
...  

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