scholarly journals Comparison of In Situ and Ex Situ Equilibrium Passive Sampling for Measuring Freely Dissolved Concentrations of Parent and Alkylated Polycyclic Aromatic Hydrocarbons in Sediments

2020 ◽  
Vol 39 (11) ◽  
pp. 2169-2179
Author(s):  
Mathias Reininghaus ◽  
Thomas F. Parkerton ◽  
Gesine Witt
1998 ◽  
Vol 38 (11) ◽  
pp. 177-185 ◽  
Author(s):  
Jean D. MacRae ◽  
Kenneth J. Hall

Polycyclic Aromatic Hydrocarbons (PAH) are common environmental pollutants that have been linked to cancerous lesions in bottom fish. In this research, the feasibility of using nitrate as an alternative electron acceptor to stimulate PAH-degradation in anoxic marine sediment was investigated. PAH could be degraded under denitrifying conditions as long as other nutrients were not limiting. The half lives of low molecular weight PAH ranged from approximately 33-88 days. Degradation of high molecular weight PAH was slower, or not observed. Half lives ranged from 143-812 days. Nitrate may be applied to sediments in situ or used in bioreactors to reduce the cost of bioremediation operations ex situ.


2015 ◽  
Vol 101 (1) ◽  
pp. 296-303 ◽  
Author(s):  
Susann-Cathrin Lang ◽  
Andrew Hursthouse ◽  
Philipp Mayer ◽  
Danjiela Kötke ◽  
Ines Hand ◽  
...  

2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.


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