Stopped-flow determination of carbon dioxide-diethanolamine reaction mechanism: Kinetics of carbamate formation

1983 ◽  
Vol 15 (11) ◽  
pp. 1147-1160 ◽  
Author(s):  
D. Barth ◽  
C. Tondre ◽  
J. J. Delpuech
Keyword(s):  
Carbon Dioxide ◽  
Reaction Mechanism ◽  
Stopped Flow ◽  
Kinetics Of

The kinetics of partial processes in the oxidation of ascorbic acid catalyzed by vanadyl tetrasulphophthalocyanine

1982 ◽  
Vol 47 (3) ◽  
pp. 744-754 ◽  
Author(s):  
Dana M. Wagnerová ◽  
Jaroslav Votruba ◽  
Jürgen Blanck ◽  
Josef Vepřek-Šiška
Keyword(s):  
Experimental Data ◽  
Ascorbic Acid ◽  
Reaction Mechanism ◽  
Rate Constants ◽  
Stopped Flow ◽  
Adaptive Identification ◽  
Flow Method ◽  
Acid Catalyzed ◽  
Kinetics Of

The rapid partial reactions of the oxidation of ascorbic acid by dioxygen with vanadyl tetrasulphophthalocyanine as a catalyst were studied by the stopped-flow method. The experimental data were treated on a computer and compared with the kinetic implications resulting from the proposed mechanism. Application of the adaptive identification method led to quantitative solution of the mechanism, i.e. determination of the values of all the isolated rate constants of the reaction mechanism.

Reaction kinetics of carbon dioxide in aqueous blends of N-methyldiethanolamine and glycine using the stopped flow technique

2016 ◽  
Vol 33 ◽  
pp. 186-195 ◽  
Author(s):  
Abdelbaki Benamor ◽  
Mohammed Jaber Al-Marri ◽  
Majeda Khraisheh ◽  
Mustafa S. Nasser ◽  
Paitoon Tontiwachwuthikul
Keyword(s):  
Carbon Dioxide ◽  
Reaction Kinetics ◽  
Stopped Flow ◽  
Kinetics Of

Oxidation of glycolaldehyde by manganese(III) sulphate

1981 ◽  
Vol 46 (10) ◽  
pp. 2509-2518
Author(s):  
Jiří Barek ◽  
Antonín Berka ◽  
Alena Pokorná-Hladíková
Keyword(s):  
Reaction Mechanism ◽  
Formic Acid ◽  
Ferrous Sulphate ◽  
Indirect Determination ◽  
Convenient Procedure ◽  
Kinetics Of

Glycolaldehyde was found to be oxidized by manganese(III) sulphate with exchange of two electrons to give formaldehyde and formic acid. The kinetics of the reaction was studied and the reaction mechanism deduced. A convenient procedure is suggested for an indirect determination of glycolaldehyde based on its oxidation with excess manganese(III) sulphate and subsequent retitration of the unreacted reagent with ferrous sulphate.

scholarly journals Kinetics of Carbon Dioxide with Amines. I. Stopped-Flow Studies in Aqueous Solutions. A Review

2013 ◽  
Vol 69 (5) ◽  
pp. 865-884 ◽  
Author(s):  
Gabriel Couchaux ◽  
Danielle Barth ◽  
Marc Jacquin ◽  
Abdelaziz Faraj ◽  
Julien Grandjean
Keyword(s):  
Carbon Dioxide ◽  
Aqueous Solutions ◽  
Stopped Flow ◽  
Kinetics Of
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