Mesoscopic Patterning in Evaporated Polymer Solutions: Poly(ethylene glycol) and Room-Temperature-Vulcanized Polyorganosilanes/-siloxanes Promote Formation of Honeycomb Structures

2008 ◽  
Vol 209 (6) ◽  
pp. 567-576 ◽  
Author(s):  
Edward Bormashenko ◽  
Alexander Malkin ◽  
Albina Musin ◽  
Yelena Bormashenko ◽  
Gene Whyman ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Room Temperature ◽  
Polymer Solutions ◽  
Poly Ethylene Glycol ◽  
Honeycomb Structures ◽  
Poly Ethylene

scholarly journals Synthesis of Network Polymers by Means of Addition Reactions of Multifunctional-Amine and Poly(ethylene glycol) Diglycidyl Ether or Diacrylate Compounds

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2047
Author(s):  
Naofumi Naga ◽  
Mitsusuke Sato ◽  
Kensuke Mori ◽  
Hassan Nageh ◽  
Tamaki Nakano
Keyword(s):  
Ethylene Glycol ◽  
Room Temperature ◽  
Addition Reaction ◽  
Monomer Concentration ◽  
Diglycidyl Ether ◽  
Porous Polymers ◽  
Addition Reactions ◽  
Poly Ethylene Glycol ◽  
Network Polymers ◽  
Poly Ethylene

Addition reactions of multi-functional amine, polyethylene imine (PEI) or diethylenetriamine (DETA), and poly(ethylene glycol) diglycidyl ether (PEGDE) or poly(ethylene glycol) diacrylate (PEGDA), have been investigated to obtain network polymers in H2O, dimethyl sulfoxide (DMSO), and ethanol (EtOH). Ring opening addition reaction of the multi-functional amine and PEGDE in H2O at room temperature or in DMSO at 90 °C using triphenylphosphine as a catalyst yielded gels. Aza-Michael addition reaction of the multi-functional amine and PEGDA in DMSO or EtOH at room temperature also yielded corresponding gels. Compression test of the gels obtained with PEI showed higher Young’s modulus than those with DETA. The reactions of the multi-functional amine and low molecular weight PEGDA in EtOH under the specific conditions yielded porous polymers induced by phase separation during the network formation. The morphology of the porous polymers could be controlled by the reaction conditions, especially monomer concentration and feed ratio of the multi-functional amine to PEGDA of the reaction system. The porous structure was formed by connected spheres or a co-continuous monolithic structure. The porous polymers were unbreakable by compression, and their Young’s modulus increased with the increase in the monomer concentration of the reaction systems. The porous polymers absorbed various solvents derived from high affinity between the polyethylene glycol units in the network structure and the solvents.

FABRICATION OF QCM TYPE SMOTHER DETECTION SENSOR BY PLASMA POLYMERIZING SnOx ORGANIC-LIKE FILMS AND SPIN COATING WITH POLY ETHYLENE GLYCOL

2012 ◽  
Vol 24 (02) ◽  
pp. 179-183
Author(s):  
Ko-Shao Chen ◽  
Shu-Chuan Liao ◽  
Hsin-Ming Wu ◽  
Yu-Chia Tsao ◽  
Hong-Ru Lin
Keyword(s):  
Thin Films ◽  
Ethylene Glycol ◽  
Spin Coating ◽  
Room Temperature ◽  
Plasma Deposition ◽  
Post Treatment ◽  
Detection Sensitivity ◽  
Poly Ethylene Glycol ◽  
Frequency Drop ◽  
Poly Ethylene

Quartz crystal microbalances (QCM) are transducers for chemical and biochemical sensing. The oscillation frequency of QCM is affected by the adsorbed mass on the surface. In this work, a new room temperature type gas sensor device fabricated by organically hybridized plasma deposition of tetramethyltin (TMT) and oxygen. Post treatment with poly ethylene glycol (PEG) was developed to detect the ambient environmental smother, and the responses of the fabricated sensor to smother detection were investigated. SnO x C y thin films on the sensor electrodes were obtained by plasma deposition from TMT and O 2 gas mixtures at room temperature. A spin coating post treatment on the SnO x C y thin films turns into hydrophilic property. The response of the QCM sensor to the smother detection shows a frequency drop during the burning of candle and has good detection sensitivity with Δf equal to 2400 Hz. Repeated smother testing with the QCM type smother detection sensor also indicates the stability of the fabricated sensor.

Deprotective activity of nanosized globular partially quaternized poly(tertiary amine)s in peptide synthesis

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Pascal Chapon ◽  
Jean Coudane ◽  
Henri Garreau ◽  
Michel Vert ◽  
Jean Alain Ferhentz ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Aqueous Medium ◽  
Room Temperature ◽  
Heterogeneous Systems ◽  
Protecting Groups ◽  
Hydrophobic Core ◽  
Poly Ethylene Glycol ◽  
Solid Supports ◽  
Spacer Arm ◽  
Poly Ethylene

AbstractBifunctional polybases of the partially quaternized poly[thio-1-(N,Ndiethylaminomethyl) ethylene] type (Q(PTDAE),X, with X = percentage of N-quaternization) are able to catalyze various reactions including lipophilic reagents temporarily entrapped in the hydrophobic core of the globules. In this contribution it is shown that benzyloxycarbonyl (Z) and fluoromethyloxycarbonyl (Fmoc) protecting groups of peptides are cleaved at room temperature in a few minutes in an aqueous medium at pH 7,4. Deprotection was also effective when peptides were attached to solid supports of the Merrifield type provided a hydrophilic spacer arm of the poly(ethylene glycol)-type was inserted between beads and the built up peptide moieties. However, unhooking was observed when the hydrophilic spacerpeptide bond was an ester but not when it was of the amide type. The work shows that Q(PTDAE),X globules exhibit enzyme-like activity in a homogeneous aqueous medium and in heterogeneous systems as well.

Room temperature aqueous self-assembly of poly(ethylene glycol)-poly(4-vinyl pyridine) block copolymers: From spherical to worm-like micelles

2016 ◽  
Vol 145 ◽  
pp. 447-453 ◽  
Author(s):  
Daniela P. Rodrigues ◽  
João R.C. Costa ◽  
Nuno Rocha ◽  
Joana R. Góis ◽  
Arménio C. Serra ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ethylene Glycol ◽  
Self Assembly ◽  
Room Temperature ◽  
Poly Ethylene Glycol ◽  
Vinyl Pyridine ◽  
Poly Ethylene

Molar mass fractionation in aqueous two-phase polymer solutions of dextran and poly(ethylene glycol)

2016 ◽  
Vol 1452 ◽  
pp. 107-115 ◽  
Author(s):  
Ziliang Zhao ◽  
Qi Li ◽  
Xiangling Ji ◽  
Rumiana Dimova ◽  
Reinhard Lipowsky ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Molar Mass ◽  
Polymer Solutions ◽  
Poly Ethylene Glycol ◽  
Two Phase ◽  
Mass Fractionation ◽  
Poly Ethylene

Thermodynamic properties of aqueous polymer solutions: poly(ethylene glycol)/dextran

1989 ◽  
Vol 93 (14) ◽  
pp. 5612-5617 ◽  
Author(s):  
C. A. Haynes ◽  
R. A. Beynon ◽  
R. S. King ◽  
H. W. Blanch ◽  
J. M. Prausnitz
Keyword(s):  
Thermodynamic Properties ◽  
Ethylene Glycol ◽  
Polymer Solutions ◽  
Poly Ethylene Glycol ◽  
Aqueous Polymer ◽  
Poly Ethylene
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