PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High‐Efficiency Protective Masks

Author(s):  
Junpeng Xiong ◽  
Weili Shao ◽  
Ling Wang ◽  
Chen Cui ◽  
Yurui Jin ◽  
...  
2018 ◽  
Vol 49 (4) ◽  
pp. 431-446
Author(s):  
Mufang Li ◽  
Yongzhi Wu ◽  
Weibing Zhong ◽  
Qinghua Zhao ◽  
Qihao Guo ◽  
...  

Filter membranes with high efficiency and low energy consumption are gaining more attention owing to the increase in water pollution. To enhance the filtration performance, a novel spindle polyurethane (PU) / poly(vinyl alcoholco-ethylene) (PVA-co-PE) composite nanofiber membrane was prepared. It is the first time that the spindle composite nanofibers and nanofiber membranes are prepared based on the PU/PVA-co-PE/CAB (cellulose acetate butyrate) immiscible polymer blends. The effects of PU concentration on the morphology, size distribution, and hydrophilicity of PU/PVA-co-PE nanofiber membranes were analyzed. The pure PVA-co-PE nanofiber membrane and PU/PVA-co-PE composite nanofiber membranes were used to filtrate the nanoparticle suspension with scarlet pigments (50–300 nm). Due to the smaller pore size, looser structure, and larger porosity, the rejection rate and flux of spindle PU/PVA-co-PE composite nanofiber membranes are both higher than that of pure PVA-co-PE nanofiber membrane. When the basic weight of nanofiber layer is 6 g/m2, the rejection rate of all the PU/PVA-co-PE membranes are above 99%. This study provided a novel, facile, and high-throughput method to prepare spindle nanofiber membranes and indicated the advantage of spindle PU/PVA-co-PE composite nanofiber membranes in the application of water filtration.


2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Yuanli Chen ◽  
Hui Fan ◽  
Xinlin Zha ◽  
Wenwen Wang ◽  
Yi Wu ◽  
...  

AbstractHigh efficiency and anti-pollution oil/water separation membrane has been widely explored and researched. There are a large number of hydroxyl groups on the surface of silica, which has good wettability and can be used for oil-water separation membranes. Hydrophilic silica nanostructures with different morphologies were synthesized by changing templates and contents of trimethylbenzene (TMB). Here, silica nanospheres with radical pores, hollow silica nanospheres and worm-like silica nanotubes were separately sprayed on the PVA-co-PE nanofiber membrane (PM). The abundance of hydroxyl groups and porous structures on PM surfaces enabled the absorption of silica nanospheres through hydrogen bonds. Compared with different silica nanostructures, it was found that the silica/PM exhibited excellent super-hydrophilicity in air and underwater “oil-hating” properties. The PM was mass-produced in our lab through melt-extrusion-phase-separation technique. Therefore, the obtained membranes not only have excellent underwater superoleophobicity but also have a low-cost production. The prepared silica/PM composites were used to separate n-hexane/water, silicone oil/water and peanut oil water mixtures via filtration. As a result, they all exhibited efficient separation of oil/water mixture through gravity-driven filtration.


RSC Advances ◽  
2020 ◽  
Vol 10 (46) ◽  
pp. 27492-27501
Author(s):  
Xiang Li ◽  
Shilin Chen ◽  
Zilong Xia ◽  
Li Li ◽  
Wenhui Yuan

In this study, a novel boehmite/polyacrylonitrile (BM/PAN) composite nanofiber membrane was prepared using the electrospinning technique.


2021 ◽  
Vol 252 ◽  
pp. 02056
Author(s):  
Xianwei Fan ◽  
Ran Zhao ◽  
Haoxuan Hu ◽  
Junyi Liu ◽  
Yahui Nie ◽  
...  

In this paper, we prepared a polyvinyl alcohol-polyethylene (PVA-Co-PE) composite nanofiber membrane catalyst decorated by Fe-MOFs/SiC and completed the photocatalytic reduction of CO2 performance. The results show that the CO2 conversion rate of composite film materials under visible light irradiation is increased by 31 times compared with powdered Fe-MOFs/SiC materials. Through SEM, XRD, BET, FTIR, DRS and other characterization methods, the influencing factors of the photocatalytic CO2 reduction process of the composite nanofiber membrane were investigated. The synergistic effect of Fe-MOFs/SiC and nanofiber membrane photocatalysis is beneficial to electron-hole pairs. The effective separation and strong absorption in the visible light region make it exhibit excellent photocatalytic activity in the photocatalytic CO2 reduction reaction.


Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1511 ◽  
Author(s):  
Baolei Shen ◽  
Dongyu Zhang ◽  
Yujuan Wei ◽  
Zihua Zhao ◽  
Xiaofei Ma ◽  
...  

Coarse wool is a kind of goat wool that is difficult to further process in the textile industry due to its large diameter, dispersion, better strength, and less bending. Therefore, coarse wool is often discarded as waste or made into low-cost products. In this work, keratin was extracted from coarse wool by a high-efficiency method, and then, an Ag-doped keratin/PA6 composite nanofiber membrane with enhanced filtration and antibacterial performance was prepared using HCOOH as solvent and reductant. HAADF-STEM (high-angle annular dark field-scanning transmission electron microscopy) shows that AgNPs are uniformly distributed in keratin/PA6 (30/70) nanofibers. TGA (Thermogravimetric Analysis) and DSC (Differential Scanning Calorimetry) were employed to investigate the thermal stability of composite membranes with different keratin and AgNP contents. The present keratin as a dopant with polyamide-6 (PA6) was found not only to improve air filtration efficiency but also to enhance water–vapour transmission (WVT). The addition of the Ag nanoparticles (AgNPs) gave a strong antibacterial activity to the composite membrane against Staphylococcus aureus (99.62%) and Escherichia coli (99.10%). Bacterial filtration efficiency (BFE) of the composite membrane against S. aureus and E. coli were up to 96.8% and 95.6%, respectively. All of the results suggested a great potential for coarse wool extraction and application in the air filtration field.


2012 ◽  
Vol 10 (1) ◽  
pp. 649-651 ◽  
Author(s):  
Jing Wei ◽  
Jingyan Liu ◽  
Jing Qiang ◽  
Lina Yang ◽  
Yuqin Wan ◽  
...  

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