The tetramethylammonium ion (TMA+) versus the hydronium ion (H3O+) as internal reference for1H NMR measurements in superacid media. Solute-solvent interactions

1981 ◽  
Vol 16 (2) ◽  
pp. 160-163 ◽  
Author(s):  
Paul Rimmelin ◽  
Sylvie Schwartz ◽  
Jean Sommer
TAPPI Journal ◽  
2010 ◽  
Vol 9 (7) ◽  
pp. 35-41
Author(s):  
OUTI A. HYÖKYVIRTA ◽  
TOM E. GUSTAFSSON

This investigation evaluated the applicability of a molybdenum sulfide reference electrode (MSRE) as an internal reference electrode for use in alkaline sulfide solutions over a range of pulp digester liquors at 170°C. The electrode remained stable during the exposure period of two weeks. The experimentally determined half cell potential of the MSRE is E = -0.91 VSHE. The surface of the MSRE was examined by scanning electron microscope (SEM) and electron spectroscopy for chemical analysis (ESCA) to verify the chemical composition of the thin surface film. Based on ESCA studies, the surface film contained molybdenum disulfide and sodium disulfide. During storage of the specimens, sulfide was partly oxidized to sodium sulfite in air. Next to the metallic molybdenum, a mixed molybdenum disulfide and molybdenum hydroxide layer was detected.


1992 ◽  
Vol 57 (11) ◽  
pp. 2227-2234 ◽  
Author(s):  
Ján Benko ◽  
Oľga Vollárová

The enthalpies of solution ∆Hs0 were determined for NaSCN, KSCN, NaBrO3, KBrO3, NaClO3, KClO3, NaIO4, KMnO4, KNO2 and NaNO2 in water-methanol mixtures. The transfer functions ∆Ht0 of the salts and anions were calculated based on the extrathermodynamic TPTB assumption. The ∆Ht0 values of the anion obtained from the sodium and potassium salts were compared. The differences observed, particularly at higher concentrations of the cosolvent, are discussed with respect to the interactions between the solvent molecules and the solute-solvent interactions.


2005 ◽  
Vol 70 (12) ◽  
pp. 2027-2037 ◽  
Author(s):  
Teresa Łuczak

Adsorption of aliphatic amines (C1-C4) at the gold electrode was studied by tensammetry. It has been established that the experimental dependence between the gold surface coverage (Θ) and the bulk amine concentration (cA) fits satisfactorily both by the Frumkin and Flory-Huggins isotherms. The standard Gibbs energy of adsorption, ∆G°ad at Emax for Θ < 0.8 has been found to increase in the order methylamine < ethylamine < propylamine < butylamine. This is rationalised in terms of surface-adsorbate, adsorbate-adsorbate and adsorbate-solvent interactions.


2000 ◽  
Vol 65 (9) ◽  
pp. 1455-1463
Author(s):  
Oľga Vollárová ◽  
Ján Benko

The solubility, partial molar volume and standard integral molar enthalpy of solution of cis- and trans-[CoCl2(en)2]Cl in water, aqueous methanol, aqueous tert-butyl alcohol and aqueous acetonitrile are reported. The transfer functions ∆Gt0, ∆Ht0 and T∆St0 as well as partial molar volumes are used to obtain information on the solute-solvent interactions. Results obtained are discussed in terms of differences in the surface charge distribution in isomeric coordination species.


Electronics ◽  
2021 ◽  
Vol 10 (13) ◽  
pp. 1556
Author(s):  
Zhengeng Yang ◽  
Hongshan Yu ◽  
Shunxin Cao ◽  
Qi Xu ◽  
Ding Yuan ◽  
...  

It is well known that many chronic diseases are associated with unhealthy diet. Although improving diet is critical, adopting a healthy diet is difficult despite its benefits being well understood. Technology is needed to allow an assessment of dietary intake accurately and easily in real-world settings so that effective intervention to manage being overweight, obesity, and related chronic diseases can be developed. In recent years, new wearable imaging and computational technologies have emerged. These technologies are capable of performing objective and passive dietary assessments with a much simplified procedure than traditional questionnaires. However, a critical task is required to estimate the portion size (in this case, the food volume) from a digital image. Currently, this task is very challenging because the volumetric information in the two-dimensional images is incomplete, and the estimation involves a great deal of imagination, beyond the capacity of the traditional image processing algorithms. In this work, we present a novel Artificial Intelligent (AI) system to mimic the thinking of dietitians who use a set of common objects as gauges (e.g., a teaspoon, a golf ball, a cup, and so on) to estimate the portion size. Specifically, our human-mimetic system “mentally” gauges the volume of food using a set of internal reference volumes that have been learned previously. At the output, our system produces a vector of probabilities of the food with respect to the internal reference volumes. The estimation is then completed by an “intelligent guess”, implemented by an inner product between the probability vector and the reference volume vector. Our experiments using both virtual and real food datasets have shown accurate volume estimation results.


2021 ◽  
Author(s):  
Cheol Hun Park ◽  
Eun Min Go ◽  
Kyung Min Lee ◽  
Chang Soo Lee ◽  
Sang Kyu Kwak ◽  
...  

Unprecedented substrate-independent polymeric 3D nanosheets were induced via simple solution casting using PEGBEM–POEM comb copolymer. A possible mechanism is the change in the polymer–solvent interactions on the surface.


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