Superior fire safety performances of chelates copper( II ) salicylaldehyde complexes with intumescent flame retardant TPU

2020 ◽  
Vol 31 (11) ◽  
pp. 2884-2895
Author(s):  
Xilei Chen ◽  
Xinyuan Zhang ◽  
Shaoping Kuang ◽  
Chuanmei Jiao ◽  
Shaoxiang Li
Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2662
Author(s):  
Sangram P. Bhoite ◽  
Jonghyuck Kim ◽  
Wan Jo ◽  
Pravin H. Bhoite ◽  
Sawanta S. Mali ◽  
...  

The compatibility and coating ratio between flame retardant materials and expanded polystyrene (EPS) foam is a major impediment to achieving satisfactory flame retardant performance. In this study, we prepared a water-based intumescent flame retardant system and methylene diphenyl diisocyanate (MDI)-coated expandable polystyrene microspheres by a simple coating approach. We investigated the compatibility, coating ratio, and fire performance of EPS- and MDI-coated EPS foam using a water-based intumescent flame retardant system. The microscopic study revealed that the water-based intumescent flame retardant materials were successfully incorporated with and without MDI-coated EPS microspheres. The cone calorimeter tests (CCTs) of the MDI-coated EPS containing water-based intumescent flame retardant materials exhibited better flame retardant performance with a lower total heat release (THR) 7.3 MJ/m2, peak heat release rate (PHRR) 57.6 kW/m2, fire growth rate (FIGRA) 2027.067 W/m2.s, and total smoke production (TSP) 0.133 m2. Our results demonstrated that the MDI-coated EPS containing water-based intumescent flame retardant materials achieved flame retarding properties as per fire safety standards.


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