Fabrication of 3D scaffolds based on fully biobased unsaturated polyester resins by microstereo-lithography

Additive Manufacturing (AM) technologies are an effective route to fabricate tailor made scaffolds for tissue engineering (TE) and regenerative medicine with microstereo-lithography (µSLA) being one of the most promising techniques to produce high quality 3D structures. Here, we report the crosslinking studies of fully biobased unsaturated polyesters (UPs) with 2-hydroxyethyl methacrylate (HEMA) as the unsaturated monomer (UM), using thermal and µSLA crosslinking processes. The resulting resins were fully characterized in terms of their thermal and mechanical properties. Determination of gel content, water contact angle (WCA), topography and morphology analysis by atomic force microscopy (AFM) and scanning electron microscopy (SEM) were also performed. The results show that the developed unsaturated polyester resins (UPRs) have promising properties for µSLA. In vitro cytotoxicity assays performed with 3T3-L1 cell lines showed that the untreated scaffolds exhibited a maximum cellular viability around 60 %, which was attributed to the acidic nature of the UPRs. The treatment of the UPRs and scaffolds with ethanol (EtOH) improved the cellular viability to 100%. The data presented in this manuscript contribute to improve the performance of biobased unsaturated polyesters in additive manufacturing.

On the Mechanism of the Steady-State Gamma Radiolysis-Induced Scissions of the Phenyl-Vinyl Polyester-Based Resins

The major societal problem of polymeric waste necessitates new approaches to break down especially challenging discarded waste streams. Gamma radiation was utilized in conjunction with varying solvent environments in an attempt to discern the efficacy of radiolysis as a tool for the deliberate degradation of model network polyesters. Our EPR results demonstrated that gamma radiolysis of neat resin and in the presence of four widely used solvents induces glycosidic scissions on the backbone of the polyester chains. EPR results clearly show the formation of alkoxy radicals and C-centered radicals as primary intermediate radiolytic products. Despite the protective role of the phenyl groups on the backbone of the radiation-induced polyester chains, the radiolytic-glycosidic scissions predominate. Among the following three solvents used in this study (water, isopropyl alcohol, and dichloromethane), the highest radiolytic yield of glycosidic scission was achieved using water. The •OH radicals produced in the radiolysis of phenyl unsaturated polyester aqueous suspensions very rapidly abstract H atoms from the methylene group, which is followed by a very rapid glycosidic scission. The lowest glycosidic yield was found in the dichloromethane solutions of these polyester resins due to scavenging by the fast electron capture reactions.

Characterisation of Fibre Reinforced Resin Concrete

Resin Concrete uses polymeric resin to replace cement concrete. Four types of polyester resins were identified with Methyl methacrylate as catalyst, calcium carbonate and fly ash as fillers along with river sand and coarse aggregate size of 10mm, 6mm were used to produce resin concrete. Seventy-two trial batches were carried out for preliminary investigation targeting compressive strength of more than 80 MPa (11.6 ksi) and four batches were shortlisted. These four batches along with the addition of glass fiber were taken for detailed investigation of stress strain behavior, young�s modulus, Poisson ratio, various correlative equations among their mechanical properties and durability properties. Developed mix can be recommended for manufacturing various polymer products.

Fast-Setting Permeable Alkyd/Polyester Composites: Moulding Sands

This paper presents the outcomes of extensive research targeting the development of high-performance alkyd and polyester resins used as binders in mould- and core-making permeable composite materials designated for large-size/complex-shape, heavy alloy-steel and cast-iron castings (0.5 to 50 tonnes): steam turbine casings (e.g., 18K360 condensing turbine), naval engine blocks and heavy machinery. The technology was implemented by Zamech/ALSTON Power. The key issues discussed here are: (1) control of resin crosslinking kinetics; slow or rapid strength development, (2) shelf-life control of pre-mixed composite, (3) improved thermo-mechanical stability; (4) kinetics of gaseous by-product emission. Optimised composite formulations (resins, crosslinkers and catalysts) allow for the flexible control of material properties and mould-/core fabrication, i.e.,: shelf-life: 10–120 min; mould stripping time: 10 min to 24 h; compressive strength: 4–6 MPa (with post-cure: 10–12 MPa); tensile strength: up to 3 MPa (after post-cure). The moulding sands developed achieved thermal resistance temperatures of up to 345 °C, which exceeded that of 280 °C of comparable commercial material. The onset of the thermal decomposition process was 2–3 times longer than that of furan or commercial alkyd/polyester resin. The technology developed allows for the defect-free manufacture of castings (no pinholes) and binder contents minimisation to 1.2–1.5% with quartz and 1.2% with zirconium or chromite sand.

Comparison of LC-ESI, DART, and ASAP for the analysis of oligomers migration from biopolymer food packaging materials in food (simulants)

Biopolymers based on polylactic acid (PLA) and starch have numerous advantages, such as coming from renewable sources or being compostable, though they can have deficiencies in mechanical properties, and for this reason, polyester resins are occasionally added to them in order to improve their properties. In this work, migration from a PLA sample and from another starch-based biopolymer to three different food simulants was studied. Attention was focused on the determination of oligomers. The analysis was first performed by ultraperformance liquid chromatography quadrupole-time-of-flight mass spectrometry (UPLC-Q-TOF–MS), which allowed the identification of the oligomers present in migration. Then, the samples were analyzed by two ambient desorption/ionization techniques directly coupled to mass spectrometry (ADI), direct analysis in real-time coupled to standardized voltage and pressure (DART-MS) and atmospheric pressure solids analysis probe (ASAP-MS). These methodologies were able to detect simultaneously the main oligomers migrants and their adducts in a very rapid and effective way. Nineteen different polyester oligomers, fourteen linear and five cyclic, composed of different combinations of adipic acid [AA], propylene glycol [PG], dipropylene glycol [DPG], 2,2-dibutyl-1,3-propanediol [DBPG], or isobutanol [i-BuOH] were detected in migration samples from PLA. In migration samples from starch-based biopolymer, fourteen oligomers from poly(butylene adipate co-terephthalate) polyester (PBAT) were identified, twelve cyclic and two linear. The results from ADI techniques showed that they are a very promising alternative tool to assess the safety and legal compliance of food packaging materials. Graphical abstract

Effects of resins on mechanical performance of polymer concrete

Cement manufacturing is currently responsible for one of the highest levels of carbon dioxide (CO2) emissions and energy consumption in construction industry. Thus, the use of sustainable binder materials instead of cement has become a worldwide issue. Previous studies have shown that polymers are a reliable and sustainable alternative to cement in construction, while polymer concretes (PCs) are seen as the biggest alternative to conventional cement concretes in the long term. In this study, the main objective is to investigate the effects of resins, which are used as binder components in polymer concrete, on the mechanical properties of the PCs. To achieve this, ten different orthophthalic unsaturated polyester resins (OUPR) that are commonly used in construction industry are considered, and fresh concrete tests and hardened concrete tests are performed on deck plates prepared with these resins. Based on the analysis results, each resin is given a performance index. The experimental results indicate that the type of resin has a significant impact on mechanical properties of polymer concrete.

WOOD-GLASS-FIBER COMPOSITE MATERIALS BASED ON POLYESTER RESINS FOR TIMBER RAILWAY SLEEPER STRUCTURES

Wood-glass-fiber composite materials (WGFCM) are used in transport construction (sleepers, switch bars, etc.). Polymer solutions based on furfuralacetone monomer (FAM) served as a matrix for the manufacture of WGFCM. The article suggests using Holex HAS- 2061 polyester resin as a matrix, which, in turn, has chemical resistance, dielectric properties, increased impact strength, having sufficient strength characteristics, and significant extensibility. For the application of the above material in the structural elements of sleepers of logging railways, it is necessary to know its operation under repeated loading. Endurance experiments were conducted at different coefficients of the load application cycle asymmetry pb=0,1; 0,3; 0,6. As a result of the experiments, the values of the endurance limit of the material under study were obtained, which allow us to conclude that it can be used in the construction of timber railway sleepers.