A conductive rubber with self‐healing ability enabled by metal‐ligand coordination

An efficient strategy to modulate the thermomechanical properties and self-healing of soft polymers has been developed by rationally selecting the metal used for supramolecular crosslinking.

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Humidity responsive self-healing based on intermolecular hydrogen bonding and metal–ligand coordination

RSC Advances ◽

10.1039/c6ra11418k ◽

2016 ◽

Vol 6 (92) ◽

pp. 89757-89763 ◽

Cited By ~ 10

Author(s):

Yanxi Zhu ◽

Hongyun Xuan ◽

Jiaoyu Ren ◽

Xuefan Liu ◽

Bo Zhao ◽

...

Keyword(s):

Hydrogen Bonding ◽

Healing Process ◽

Intermolecular Hydrogen Bonding ◽

Self Healing ◽

Ligand Coordination ◽

Metal Ligand

Self-healing process occurring when a self-healing Co–CS/PAA PEM film is integrated (I), damaged (II), self-healing (III), and self-healed (IV).

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Stretchable Self-Healing Polymeric Dielectrics Cross-Linked Through Metal–Ligand Coordination

Journal of the American Chemical Society ◽

10.1021/jacs.6b02428 ◽

2016 ◽

Vol 138 (18) ◽

pp. 6020-6027 ◽

Cited By ~ 216

Author(s):

Ying-Li Rao ◽

Alex Chortos ◽

Raphael Pfattner ◽

Franziska Lissel ◽

Yu-Cheng Chiu ◽

...

Keyword(s):

Self Healing ◽

Ligand Coordination ◽

Polymeric Dielectrics ◽

Metal Ligand

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Self-Healing, Highly Sensitive Electronic Sensors Enabled by Metal–Ligand Coordination and Hierarchical Structure Design

ACS Applied Materials & Interfaces ◽

10.1021/acsami.7b05204 ◽

2017 ◽

Vol 9 (23) ◽

pp. 20106-20114 ◽

Cited By ~ 54

Author(s):

Yangyang Han ◽

Xiaodong Wu ◽

Xinxing Zhang ◽

Canhui Lu

Keyword(s):

Hierarchical Structure ◽

Structure Design ◽

Self Healing ◽

Highly Sensitive ◽

Ligand Coordination ◽

Electronic Sensors ◽

Metal Ligand

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Self-Assembled Nanomaterials Based on Complementary Sn(IV) and Zn(II)-Porphyrins, and Their Photocatalytic Degradation for Rhodamine B Dye

Molecules ◽

10.3390/molecules26123598 ◽

2021 ◽

Vol 26 (12) ◽

pp. 3598

Author(s):

Nirmal K. Shee ◽

Hee-Joon Kim

Keyword(s):

Aqueous Solution ◽

Visible Light Irradiation ◽

Rhodamine B ◽

Self Assembly ◽

The Self ◽

Assembly Process ◽

Absorption Bands ◽

Ligand Coordination ◽

Rhodamine B Dye ◽

Metal Ligand

A series of porphyrin triads (1–6), based on the reaction of trans-dihydroxo-[5,15-bis(3-pyridyl)-10,20-bis(phenyl)porphyrinato]tin(IV) (SnP) with six different phenoxy Zn(II)-porphyrins (ZnLn), was synthesized. The cooperative metal–ligand coordination of 3-pyridyl nitrogens in the SnP with the phenoxy Zn(II)-porphyrins, followed by the self-assembly process, leads to the formation of nanostructures. The red-shifts and remarkable broadening of the absorption bands in the UV–vis spectra for the triads in CHCl3 indicate that nanoaggregates may be produced in the self-assembly process of these triads. The emission intensities of the triads were also significantly reduced due to the aggregation. Microscopic analyses of the nanostructures of the triads reveal differences due to the different substituents on the axial Zn(II)-porphyrin moieties. All these nanomaterials exhibited efficient photocatalytic performances in the degradation of rhodamine B (RhB) dye under visible light irradiation, and the degradation efficiencies of RhB in aqueous solution were observed to be 72~95% within 4 h. In addition, the efficiency of the catalyst was not impaired, showing excellent recyclability even after being applied for the degradation of RhB in up to five cycles.

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