ESR study of the macroradicals produced in polycarbonate by thermal decomposition of benzoyl peroxide at high pressure

1976 ◽  
Vol 14 (6) ◽  
pp. 1549-1551 ◽  
Author(s):  
J. Plaček ◽  
F. Szőcs ◽  
E. Borsig
Keyword(s):  
Thermal Decomposition ◽  
High Pressure ◽  
Benzoyl Peroxide

THE THERMAL DECOMPOSITION OF HEXAFLUOROAZOMETHANE

1962 ◽  
Vol 40 (5) ◽  
pp. 930-934 ◽  
Author(s):  
Elizabeth Leventhal ◽  
Charles R. Simonds ◽  
Colin Steel
Keyword(s):  
Thermal Decomposition ◽  
High Pressure ◽  
Rate Constant ◽  
Static System ◽  
Homogeneous Reaction

The pyrolysis of hexafluoroazomethane has been studied in a static system between 0.3 mm and 73 mm and 572 °K and 634 °K by measuring the rate of nitrogen formation. The rate constant of the high-pressure homogeneous reaction is given by k = 1016.17±0.15 exp (−55,200 ± 400/RT) sec−1

High-Resolution Electron Microscopy Studies of Faults and Intergrowth in Nb3O7F

1990 ◽  
Vol 183 ◽  
Author(s):  
Lotta permér ◽  
Monica Lundberg
Keyword(s):  
Electron Microscopy ◽  
Thermal Decomposition ◽  
High Pressure ◽  
High Resolution Electron Microscopy ◽  
Two Dimensions ◽  
Resolution Electron ◽  
Shear Type ◽  
Pressure Form ◽  
The Common ◽  
Shear Planes

AbstractHREM studies of the low-pressure form of Nb3O7F, obtained by thermal decomposition of NbO2F or by reacting stoichiometric amounts of NbO2F and Nb2O5, confirmed that the crystals are built up of a shear-type structure in which slabs of ReO3 type, infinite in two dimensions and three octahedra wide, separate the shear planes. Most of the crystals were well-ordered, although faults could occasionally be detected. However, some crystals were found to be intergrown with a structure closely related to the high-pressure form of Nb3O7F. The latter structure is composed of wavy rows of edge-sharing NbX7 pentagonal bipyramids, joined to each other by NbX6 octahedra. The connection between the two atomic arrangements can be understood in terms of the common c-axes and a slight distortion of the polyhedra along the boundary.

High-Pressure Thermal Decomposition of Tetrahydrotricyclopentadiene (THTCPD) and Binary High-Density Hydrocarbon Fuels of JP-10/THTCPD in a Tubular Flowing Reactor

2017 ◽  
Vol 31 (8) ◽  
pp. 8023-8035 ◽  
Author(s):  
Xueke Jia ◽  
Baoman Guo ◽  
Baitang Jin ◽  
Xiangwen Zhang ◽  
Kai Jing ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
High Pressure ◽  
High Density ◽  
Hydrocarbon Fuels

Mechanism of reactions initiated by thermal decomposition of benzoyl peroxide in polyamide

1982 ◽  
Vol 24 (12) ◽  
pp. 2991-3000 ◽  
Author(s):  
G.G. Makarov ◽  
Yu.A. Mikheyev ◽  
G.B. Pariiskii ◽  
L.M. Postnikov ◽  
D.A. Toptygin
Keyword(s):  
Thermal Decomposition ◽  
Benzoyl Peroxide
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