Synthesis of H-shaped A3BA3 copolymer by methyl-2-nitrosopropane induced single electron transfer nitroxide radical coupling

2011 ◽  
Vol 49 (13) ◽  
pp. 2811-2817 ◽  
Author(s):  
Zhongning Zhang ◽  
Guowei Wang ◽  
Junlian Huang
Keyword(s):  
Electron Transfer ◽  
Nitroxide Radical ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Coupling

Mononuclear manganese(iii) complexes with reduced imino nitroxide radicals by single-electron transfer and intermolecular hydrogen bonds as an intramolecular structural driving force

2019 ◽  
Vol 48 (35) ◽  
pp. 13378-13387 ◽  
Author(s):  
Constance Lecourt ◽  
Warren Madanamoothoo ◽  
Vivian Ferreol ◽  
Nicolas Bélanger-Desmarais ◽  
Lhoussain Khrouz ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Bonds ◽  
Crystal Structures ◽  
Driving Force ◽  
Nitroxide Radical ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Nitroxide Radicals ◽  
Intermolecular Hydrogen Bonds ◽  
Imino Nitroxide

One-electron transfer from Mn(ii) ions to an imino nitroxide radical gives mononuclear Mn(iii) complexes of the reduced amino imine-oxide form for which crystal structures evidence hydrogen bonds networks acting as a stabilizing driving-force.

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

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