Tuning nanoscopic self-assembly of diblock copolymer blends on a two-dimensional interface

2010 ◽  
Vol 49 (2) ◽  
pp. 136-143 ◽  
Author(s):  
Hsiang-Wei Lu ◽  
Jennifer L. Logan ◽  
A. E. Hosoi ◽  
Shenda M. Baker
Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3310
Author(s):  
Shengda Liu ◽  
Jiayun Xu ◽  
Xiumei Li ◽  
Tengfei Yan ◽  
Shuangjiang Yu ◽  
...  

In the past few decades, enormous efforts have been made to synthesize covalent polymer nano/microstructured materials with specific morphologies, due to the relationship between their structures and functions. Up to now, the formation of most of these structures often requires either templates or preorganization in order to construct a specific structure before, and then the subsequent removal of previous templates to form a desired structure, on account of the lack of “self-error-correcting” properties of reversible interactions in polymers. The above processes are time-consuming and tedious. A template-free, self-assembled strategy as a “bottom-up” route to fabricate well-defined nano/microstructures remains a challenge. Herein, we introduce the recent progress in template-free, self-assembled nano/microstructures formed by covalent two-dimensional (2D) polymers, such as polymer capsules, polymer films, polymer tubes and polymer rings.


2019 ◽  
Vol 58 (30) ◽  
pp. 10173-10178 ◽  
Author(s):  
Hao Tian ◽  
Jieqiong Qin ◽  
Dan Hou ◽  
Qian Li ◽  
Chen Li ◽  
...  

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.


2007 ◽  
Vol 204 (6) ◽  
pp. 1856-1862 ◽  
Author(s):  
Ching-Ling Hsu ◽  
Szu-Ming Chu ◽  
Kiwi Wood ◽  
Yi-Rong Yang

2006 ◽  
Vol 16 (18) ◽  
pp. NA-NA
Author(s):  
S. Kronholz ◽  
S. Rathgeber ◽  
S. Karthäuser ◽  
H. Kohlstedt ◽  
S. Clemens ◽  
...  

Author(s):  
Seung Hyun Kim ◽  
Hwi Sun Lee ◽  
Moo Sung Lee ◽  
Won Ho Jo

2009 ◽  
Vol 5 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Hareem T. Maune ◽  
Si-ping Han ◽  
Robert D. Barish ◽  
Marc Bockrath ◽  
William A. Goddard III ◽  
...  

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