Corrosion inhibition by benzotriazole derivatives and sodium dodecyl sulphate as corrosion inhibitors for copper in ground water at different temperatures

2015 ◽  
Vol 47 (5) ◽  
pp. 618-625 ◽  
Author(s):  
D. Gopi ◽  
El‐Sayed M. Sherif ◽  
M. Surendiran ◽  
D. M. Angeline Sakila ◽  
L. Kavitha
2010 ◽  
Vol 2 (2) ◽  
pp. 313-321 ◽  
Author(s):  
K. M. A. Haque ◽  
M. S. Hussain

Nano-sized nickel particles have been synthesized by a bottom-up approach, using hydrazine as the reducing agent in the presence of an anionic surfactant - sodium-dodecyl sulphate (SDS). The effect of adding a nonionic polymer -polyvinylpyrrolidone (PVP) with an anionic surfactant has been studied at two different temperatures; the rate of reduction increased as the reaction temperature was increased from 60 to 100°C. These nano-aggregated nickel particles were characterized by using SEM with EDX facilities and TEM. TEM characterization showed the presence of spherical Ni particles as fine as 10nm in diameter. However, the SEM images showed a very spiky morphology, very small spherical shaped objects were clearly observed within these spiky structures. The combination of SDS/PVP reaction produced nano-sized nickel particles which were much finer than the reactions where SDS was used on its own. PVP has shown some dispersion power, and was found to be capable of preventing nickel particles from gradual agglomeration.  Keywords: Bottom-up; SDS; PVP; 10 nm. © 2010 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.       DOI:10.3329/jsr.v2i2.3261               J. Sci. Res. 2 (2), 313-321 (2010) 


2012 ◽  
Vol 37 (5) ◽  
pp. 1313-1325 ◽  
Author(s):  
A. Leema Rose ◽  
A. Peter Pascal Regis ◽  
Susai Rajendran ◽  
A. Krishnaveni ◽  
Felicia Rajammal Selvarani

2017 ◽  
Vol Volume-2 (Issue-1) ◽  
pp. 652-661
Author(s):  
P. seethalakshmi ◽  
K. Renuka Devi ◽  
R.Seema | J. Benazir Jiya ◽  

The classical work of McBain on the electrical conductivity and other properties of aqueous solutions of the soaps led him to postulate the formation of the ionic micelle. This aggregate of ions has a greater mobility than that of the ions composing it, and its formation accounts for the characteristic increase in conductivity exhibited by colloidal electrolytes. The conception has resulted in great advance in the study of all classes of colloidal electrolytes e. g ., protein and gelatine salts, dyes, and other substances of high molecular weight.


2011 ◽  
Vol 66 (5) ◽  
pp. 345-352
Author(s):  
Anwar Ali ◽  
Firdoos Ahmad Itoo ◽  
Nizamul Haque Ansari

The density ρ, and viscosity η of 0.00, 0.05, 0.10, 0.15, and 0.20 mol kg−1 glycine (Gly), dlalanine (Ala), dl-serine (Ser), and dl-valine (Val) have been measured in 0.002 mol kg−1 aqueous sodium dodecyl sulphate (SDS) at 298.15, 303.15, 308.15, and 313.15 K. These data have been used to calculate the apparent molar volume φv, infinite dilution apparent molar volume φv°, and the standard partial molar volumes of transfer φv° (tr), of the amino acids from water to the aqueous SDS solutions. Falkenhagen coefficient A, Jones-Dole coefficient B, free energies of activation per mole of solvent (aqueous SDS) Δμ1°*, and per mole solute (amino acids) Δμ2°*, also enthalpy ΔH* and entropy ΔS* of activation of viscous flow were evaluated using viscosity data. The molar refraction RD was calculated by using experimental values of the refractive index nD of the systems. The results have been interpreted in terms of ion-ion, ion-polar and hydrophobic-hydrophobic group interactions. The volume of the transfer data suggest that ion-ion intertactions are predominant.


2014 ◽  
Vol 6 (5) ◽  
pp. 63-67
Author(s):  
A. Gomathiyalini ◽  
◽  
K. Renuka Devi ◽  
S. Rathika ◽  
S. Geetha

2016 ◽  
Vol 63 (2) ◽  
pp. 30-36
Author(s):  
L. Stopková ◽  
A. Hriňaková ◽  
Ž. Bezáková ◽  
F. Andriamanty ◽  
V. Žufková

AbstractIn this manuscript was investigated behaviour of drug valsartan by micellar media of anionic surfactant sodium dodecyl sulphate. As the method was used electrical conductivity for the determination of critical micelle concentration at different temperatures (T = 293.15 - 313.15 K), as well as calculated thermodynamic parameters like standard Gibbs free energy, enthalpy and entropy of micellization. According to contribution of Gibbs free energy is the process of micellization primarily controlled by entropy. Solubilization of valsartan was studied in surfactant system at 298.15 K and physiological conditions pH 7.4 using UV-spectrophotometry at different concentration range (0.001 - 0.07 mol/l) of sodium dodecyl sulphate. The solubilization of drug was observed with increasing concentration of surfactant in aqueous solution.


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