Chiral Amino-Acid-Amide Based Ionic Liquids as a Stereoselective Organocatalyst in Asymmetric Transfer Hydrogenation of Acetophenone at Room-Temperature

2018 ◽  
Vol 3 (9) ◽  
pp. 2623-2625 ◽  
Author(s):  
Balasaheb R. Javle ◽  
Anil K. Kinage
Keyword(s):  
Ionic Liquids ◽  
Amino Acid ◽  
Room Temperature ◽  
Acid Amide ◽  
Transfer Hydrogenation ◽  
Amino Acid Amide ◽  
Asymmetric Transfer Hydrogenation

Amino Acid Amide based Ionic Liquid as an Efficient Organo-Catalyst for Solvent-free Knoevenagel Condensation at Room Temperature

2019 ◽  
Vol 149 (9) ◽  
pp. 2368-2375 ◽  
Author(s):  
Pralhad A. Burate ◽  
Balasaheb R. Javle ◽  
Pranjal H. Desale ◽  
Anil K. Kinage
Keyword(s):  
Ionic Liquid ◽  
Amino Acid ◽  
Room Temperature ◽  
Knoevenagel Condensation ◽  
Acid Amide ◽  
Solvent Free ◽  
Amino Acid Amide

scholarly journals Design of Iridium N-Heterocyclic Carbene Amino Acid Catalysts for Asymmetric Transfer Hydrogenation of Aryl Ketones

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 671
Author(s):  
Chad M. Bernier ◽  
Joseph S. Merola
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Enantiomeric Excess ◽  
Transfer Hydrogenation ◽  
Acid Catalysts ◽  
Asymmetric Transfer Hydrogenation ◽  
Reaction Conditions ◽  
Chiral Complexes ◽  
Acetophenone Derivatives ◽  
Aryl Ketones

A series of chiral complexes of the form Ir(NHC)2(aa)(H)(X) (NHC = N-heterocyclic carbene, aa = chelated amino acid, X = halide) was synthesized by oxidative addition of -amino acids to iridium(I) bis-NHC compounds and screened for asymmetric transfer hydrogenation of ketones. Following optimization of the reaction conditions, NHC, and amino acid ligands, high enantioselectivity was achieved when employing the Ir(IMe)2(l-Pro)(H)(I) catalyst (IMe = 1,3-dimethylimidazol-2-ylidene), which asymmetrically reduces a range of acetophenone derivatives in up to 95% enantiomeric excess.

N-(Fluorenyl-9-methoxycarbonyl)amino Acid Amide Derivatives as a New Class of Anti-cancer Agents

2009 ◽  
pp. 465-466 ◽  
Author(s):  
Lajos Gera ◽  
Daniel C. Chan ◽  
Vitalija Simkeviciene ◽  
Paul A. Jr Bunn ◽  
John M. Stewart
Keyword(s):  
Amino Acid ◽  
Acid Amide ◽  
Amino Acid Amide ◽  
New Class ◽  
Amide Derivatives ◽  
Anti Cancer

Cholinium-amino acid based ionic liquids: a new method of synthesis and physico-chemical characterization

2015 ◽  
Vol 17 (32) ◽  
pp. 20687-20698 ◽  
Author(s):  
Serena De Santis ◽  
Giancarlo Masci ◽  
Francesco Casciotta ◽  
Ruggero Caminiti ◽  
Eleonora Scarpellini ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Amino Acid ◽  
Room Temperature ◽  
Chemical Characterization ◽  
New Method ◽  
Room Temperature Ionic Liquids ◽  
Synthetic Method ◽  
Chemical Structures ◽  
Physico Chemical ◽  
Wide Range

Fourteen cholinium-amino acid based room temperature ionic liquids were prepared using a cleaner synthetic method. Chemicophysical properties were well correlated with the wide range of amino acid chemical structures.

Third-Generation Amino Acid Furanoside-Based Ligands from d -Mannose for the Asymmetric Transfer Hydrogenation of Ketones: Catalysts with an Exceptionally Wide Substrate Scope

2016 ◽  
Vol 358 (24) ◽  
pp. 4006-4018 ◽  
Author(s):  
Jèssica Margalef ◽  
Tove Slagbrand ◽  
Fredrik Tinnis ◽  
Hans Adolfsson ◽  
Montserrat Diéguez ◽  
...  
Keyword(s):  
Amino Acid ◽  
Transfer Hydrogenation ◽  
Third Generation ◽  
Asymmetric Transfer Hydrogenation

Aminocarbonylation of 4-Iodo-1H-imidazoles with an Amino Acid Amide Nucleophile: Synthesis of Constrained H-Phe-Phe-NH2 Analogues

2013 ◽  
Vol 78 (23) ◽  
pp. 12251-12256 ◽  
Author(s):  
Anna Skogh ◽  
Rebecca Fransson ◽  
Christian Sköld ◽  
Mats Larhed ◽  
Anja Sandström
Keyword(s):  
Amino Acid ◽  
Acid Amide ◽  
Amino Acid Amide

ChemInform Abstract: Modular Amino Acid Amide Chiral Ligands for Enantioselective Addition of Diethylzinc to Aromatic Aldehydes.

ChemInform ◽  
2011 ◽  
Vol 42 (41) ◽  
pp. no-no
Author(s):  
Shaohua Gou ◽  
Zhongbin Ye ◽  
Jing Chang ◽  
Guangjun Gou ◽  
Mingming Feng
Keyword(s):  
Amino Acid ◽  
Acid Amide ◽  
Aromatic Aldehydes ◽  
Chiral Ligands ◽  
Amino Acid Amide ◽  
Enantioselective Addition

The structure of pinnatanine, a new amino acid amide from L.

1971 ◽  
Vol 12 (47) ◽  
pp. 4477-4480 ◽  
Author(s):  
M.D Grove ◽  
M.E Daxenbichler ◽  
D. Weisleder ◽  
C.H VanEtten
Keyword(s):  
Amino Acid ◽  
Acid Amide ◽  
Amino Acid Amide
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