The Determination of The Mixing Height: An Extended Version of The Safe_Air Dispersion Model

Author(s):  
Emilia Georgieva ◽  
Elisa Canepa ◽  
Corrado F. Ratto
Author(s):  
Petra Seibert ◽  
Frank Beyrich ◽  
Sven-Erik Gryning ◽  
Sylvain Joffre ◽  
Alix Rasmussen ◽  
...  

2015 ◽  
Vol 36 (4) ◽  
pp. 3-24 ◽  
Author(s):  
Wilfried Roetzel ◽  
Chakkrit Na Ranong

Abstract An evaluation method is developed for single blow experiments with liquids on heat exchangers. The method is based on the unity Mach number dispersion model. The evaluation of one experiment yields merely one equation for the two unknowns, the number of transfer units and the dispersive Peclet number. Calculations on an example confirm that one single blow test alone cannot provide reliable values of the unknowns. A second test with a liquid of differing heat capacity is required, or a tracer experiment for the measurement of the Peclet number. A modified method is developed for gases. One experiment yields the effective number of transfer units and approximate values of the two unknowns. The numerical evaluation of calculated experiments demonstrates the applicability of the evaluation methods.


2009 ◽  
Vol 2 (4) ◽  
pp. 1663-1692 ◽  
Author(s):  
B. Zhou ◽  
S. N. Yang ◽  
S. S. Wang ◽  
T. Wagner

Abstract. A new method for the determination of the Mixing layer Height (MH) by the DOAS technique is proposed in this article. The MH can be retrieved by a combination of active DOAS and passive DOAS observations of atmospheric trace gases; here we focus on observations of NO2. Because our observations are sensitive to the vertical distribution of trace gases, we refer to the retrieved layer height as an ''effective trace gas mixing height'' (ETMH). By analyzing trace gas observations in Shanghai over one year (1017 hourly means in 93 days in 2007), the retrieved ETMH was found to range between 0.1 km and 2.8 km (average is 0.78 km); more than 90% of the measurements yield an ETMH between 0.2 km and 2.0 km. The seasonal and diurnal variation of the ETMH shows good agreement with mixing layer heights derived from meteorological observations. We investigated the relationship of the derived ETMH to temperature and wind speed and found correlation coefficients of 0.65 and 0.37, respectively. Also the wind direction has an impact on the measurement to some extent. Especially in cases when the air flow comes from highly polluted areas and the atmospheric lifetime of NO2 is long (e.g. in winter), the NO2 concentration at high altitudes over the measurement site can be enhanced, which leads to an overestimation of the ETMH. Enhanced NO2 concentrations in the free atmosphere and heterogeneity within the mixing layer can cause additional uncertainties. Our method could be easily extended to other species like e.g. SO2, HCHO or Glyoxal. Simultaneous studies of these molecules could yield valuable information on their respective atmospheric lifetimes.


1993 ◽  
Vol 58 (9) ◽  
pp. 2047-2058
Author(s):  
Zdeněk Palatý

The paper deals with determination of parameters of a dispersion model used for describing the flow of liquid on a plate with mobile packing in the region of gas velocities up to 1.5 m s-1. The parameters of the model - the diffusion Peclet number and mean residence time of liquid - were determined from the nonideal input impulse of tracer concentration and its response by the method of numerical integration of differential equation with subsequent optimization of parameters. The results of measurements are presented graphically and in the form of criterion equations.


1979 ◽  
Vol 44 (9) ◽  
pp. 2583-2597 ◽  
Author(s):  
Václav Linek ◽  
Jiří Stejskal ◽  
Jiří Sinkule ◽  
Václav Vacek

A dynamic method for the determination of volumetric mass transfer coefficient of oxygen, kLa, in bubble columns using an oxygen electrode was derived on the basis of a liquid phase axial dispersion model The influence of aeration startup was studied assuming that the kLa value is position and time dependent. The conditions are defined under which the influence of aeration startup and of axial mixing of the liquid upon the steady state kLa value is negligible. A critical assessment has been made of various methods proposed for evaluation of oxygen probe responses.


2015 ◽  
Vol 350 ◽  
pp. 149-155 ◽  
Author(s):  
David Nečas ◽  
Jiří Vodák ◽  
Ivan Ohlídal ◽  
Miloslav Ohlídal ◽  
Abhijit Majumdar ◽  
...  

2018 ◽  
Vol 96 (7) ◽  
pp. 730-737 ◽  
Author(s):  
Xibo Feng ◽  
Alberto Otero-de-la-Roza ◽  
Erin R. Johnson

Atomic and molecular dispersion coefficients can now be calculated routinely using density-functional theory. In this work, we present the first determination of how electronic excitation affects molecular C6 London dispersion coefficients from the exchange-hole dipole moment (XDM) dispersion model. Excited states are typically found to have larger dispersion coefficients than the corresponding ground states, due to their more diffuse electron densities. A particular focus is both intramolecular and intermolecular charge-transfer excitations, which have high absorbance intensities and are important in organic dyes, light-emitting diodes, and photovoltaics. In these classes of molecules, the increase in C6 for the electron-accepting moiety is largely offset by a decrease in C6 for the electron-donating moiety. As a result, the change in dispersion energy for a chromophore interacting with neighbouring molecules in the condensed phase is minimal.


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