Organic semiconductors, comparative tables comparative table on solid state photoelectron emission yield curves

Author(s):  
Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1666 ◽  
Author(s):  
Issac Torres ◽  
Mauro Ruiz ◽  
Hung Phan ◽  
Noemi Dominguez ◽  
Jacobo Garcia ◽  
...  

Organic semiconductor materials composed of π–π stacking aromatic compounds have been under intense investigation for their potential uses in flexible electronics and other advanced technologies. Herein we report a new family of seven π–π stacking compounds of silver(I) bis-N-(4-pyridyl) benzamide with varying counterions, namely [Ag(NPBA)2]X, where NPBA is N-(4-pyridyl) benzamine, X = NO3− (1), ClO4− (2), CF3SO3− (3), PF6− (4), BF4− (5), CH3PhSO3− (6), and PhSO3− (7), which form extended π−π stacking networks in one-dimensional (1D), 2D and 3D directions in the crystalline solid-state via the phenyl moiety, with average inter-ring distances of 3.823 Å. Interestingly, the counterions that contain π–π stacking-capable groups, such as in 6 and 7, can induce the formation of mesomorphic phases at 130 °C in dimethylformamide (DMF), and can generate highly branched networks at the mesoscale. Atomic force microscopy studies showed that 2D interconnected fibers form right after nucleation, and they extend from ~30 nm in diameter grow to reach the micron scale, which suggests that it may be possible to stop the process in order to obtain nanofibers. Differential scanning calorimetry studies showed no remarkable thermal behavior in the complexes in the solid state, which suggests that the mesomorphic phases originate from the mechanisms that occur in the DMF solution at high temperatures. An all-electron level simulation of the band gaps using NRLMOL (Naval Research Laboratory Molecular Research Library) on the crystals gave 3.25 eV for (1), 3.68 eV for (2), 1.48 eV for (3), 5.08 eV for (4), 1.53 eV for (5), and 3.55 eV for (6). Mesomorphic behavior in materials containing π–π stacking aromatic interactions that also exhibit low-band gap properties may pave the way to a new generation of highly branched organic semiconductors.


2021 ◽  
Vol 130 (13) ◽  
pp. 135305
Author(s):  
C. Rigoudy ◽  
K. Makasheva ◽  
M. Belhaj ◽  
S. Dadouch ◽  
G. Teyssedre ◽  
...  

2022 ◽  
Author(s):  
Alana Dixon ◽  
Herve Vezin ◽  
Thuc-Quyen Nguyen ◽  
G. N. Manjunatha Reddy

Molecular doping strategies facilitate orders of magnitudes enhancements in the charge carrier mobility of organic semiconductors (OSCs). Understanding the mechanisms of different doping strategies for OSCs and molecular-level constraints on...


1997 ◽  
Vol 91 (5) ◽  
pp. 851-857 ◽  
Author(s):  
J.B. Pełka ◽  
S. Lagomarsino ◽  
A. Cedola ◽  
S. Di Fonzo ◽  
W. Jark

2011 ◽  
Vol 44 (2) ◽  
pp. 98-104
Author(s):  
Naoki Noguchi ◽  
Haruki Asatani ◽  
Masakuni Matsuoka

2019 ◽  
Vol 43 (42) ◽  
pp. 16468-16477
Author(s):  
Zohreh S. Ghavami ◽  
Gholamhossein Grivani

The new nano size ionic metallo-Schiff base polymers (IMSPs) were synthesized by reaction of Schiff base ligand of L and VO (acac)2, ZnCl2 and CuCl2. The solid state conductivity measurements candidate them as new metallo-organic semiconductors.


2007 ◽  
Vol 16 (4-7) ◽  
pp. 823-825 ◽  
Author(s):  
D. Takeuchi ◽  
C.E. Nebel ◽  
S. Yamasaki

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