Population kinetics of the A2?i and B2?+ electronic states of CN molecules on a shock wave front

1979 ◽  
Vol 31 (1) ◽  
pp. 927-929 ◽  
Author(s):  
L. B. Ibragimova
Author(s):  
Sobieslaw Gacek ◽  
Xinwei Wang

In this work, the dynamics of the shock wave in laser-ablated argon plume with its evolution through the background gas is explored at the atomic level. Molecular Dynamics (MD) simulations have been conducted which give the insight into atomistic scale interaction and correlation effects of the propagating shock wave in the background medium. The supersonic shock wave front carries inherent sharp increase in density, temperature, and pressure. These thermodynamic parameters of the expanding shock wave are evaluated with emphasis on the kinetics of the shock wave front. The position of the shock wave front has been defined and determined over nanoseconds. Extensive research is elaborated upon to study the inside structural evolution of the shock wave and the effect of optical absorption depth.


1971 ◽  
Vol 35 (6) ◽  
pp. 419-420 ◽  
Author(s):  
G.K. Tumakev ◽  
T.V. Zhikhareva ◽  
V.R. Lazovskaya

Author(s):  
A.I. Bryzgalov

We used the model of a five-component air mixture flow behind the front of a one-dimensional shock wave to compute the flow parameters for shock front temperatures of up to 7000 K, taking into account the variable composition, translational and vibrational temperatures and pressure in the relaxation zone. Vibrational level population in oxygen and nitrogen obeys the Boltzmann distribution with one common vibrational temperature. We consider the effect that temperature nonequilibrium has on the chemical reaction rate by introducing a nonequilibrium factor to the reaction rate constant, said factor depending on the vibrational and translational temperatures. We compared our calculation results for dissociation behind the shock front to the published data concerning temperature nonequilibrium in a pure oxygen flow behind a shock wave front for two different intensities of the latter. The comparison shows a good agreement between the vibrational temperature, experimental data and calculations based on the experimental values of vibrational temperature and molality. We computed the parameters of thermodynamically nonequilibrium dissociation in the air behind the shock wave front, comparing them to those of equilibrium dissociation and calculation results previously published by others. The study demonstrates that the molality values computed converge gradually with those found in published data as the distance from the shock front increases. We list the reasons for the discrepancy between our calculation results and previously published data


1975 ◽  
Vol 9 (3) ◽  
pp. 378-380 ◽  
Author(s):  
V. F. Nesterenko ◽  
A. M. Staver ◽  
B. K. Styron

2021 ◽  
pp. 2150330
Author(s):  
Kai Yang ◽  
Quan-Yu Xu ◽  
Xiao Wu ◽  
Xiao-Juan Ma

Geometric similarity ratio is one of the important factors that affects the disturbance amplitude of shock-wave front in viscosity measurement. In this paper, the Euler difference scheme of two-dimensional (2D) equations of viscous fluid mechanics is used to simulate the disturbance amplitude damping curves under different geometric similarity ratios, and the corresponding numerical solutions are shown. The samples of aluminum shocked to 80 GPa are taken as an example. The simulation results show that the initial conditions, material viscosity, wavelength, and sample geometric similarity ratio affect the evolution of the shock front sine wave disturbance. For flyer-impact flow field, the phase shift increases from 0 to a certain value with the viscosity coefficient for sample with wavelength [Formula: see text] mm and geometric similarity ratio [Formula: see text], 0.1. So, the geometric similarity method can be used to measure the viscosity of material. But it is found that the phase shift is sensitive to the geometric similarity ratio, which should be considered in Zaidel’s equation. So, some flyer-impact experiments will be carried out to determine the simulation results, and find the quantity relation of phase shift and viscosity of material in the future investigation.


2021 ◽  
Vol 53 (2) ◽  
pp. 025504
Author(s):  
Gaku Fukushima ◽  
Jiaxi Wei ◽  
Shingo Ogawa ◽  
Jun Hagiwara ◽  
Yusuke Nakamura ◽  
...  

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