The relationship between the microstructure and microwave dielectric properties of zirconium titanate ceramics

1996 ◽  
Vol 31 (10) ◽  
pp. 2539-2549 ◽  
Author(s):  
F. Azough ◽  
R. Freer ◽  
C. -L. Wang ◽  
G. W. Lorimer
1993 ◽  
Vol 32 (Part 1, No. 9B) ◽  
pp. 4327-4331 ◽  
Author(s):  
Junichi Takahashi ◽  
Keisuke Kageyama ◽  
Kouhei Kodaira

2018 ◽  
Vol 47 (44) ◽  
pp. 15808-15815 ◽  
Author(s):  
Hongcheng Yang ◽  
Shuren Zhang ◽  
Hongyu Yang ◽  
Ying Yuan ◽  
Enzhu Li

The relationship between structure, bond characterizations and microwave dielectric properties of NdNb1−x(Al1/3W2/3)xO4 (0.03 ≤ x ≤ 0.07) ceramics was characterized by complex chemical bond theory and IR spectrum.


2003 ◽  
Vol 86 (3) ◽  
pp. 511-513 ◽  
Author(s):  
Antonio Feteira ◽  
Kumaravinothan Sarma ◽  
Neil McN. Alford ◽  
Ian M. Reaney ◽  
Derek C. Sinclair

2008 ◽  
Vol 368-372 ◽  
pp. 179-182
Author(s):  
Zong Chi Liu ◽  
Dong Xiang Zhou ◽  
Shu Ping Gong

The effects of CuO-MoO3 addition on the sintering behavior and microwave dielectric properties of ZnO-TiO2 ceramics were investigated. ZnO-TiO2 ceramics were prepared with conventional solid-state method and sintered at temperatures from 850 to 1050 °C. The sintering temperature of ZnO-TiO2 ceramics with CuO-MoO3 addition could be effectively reduced to 950 °C due to the liquid phase effects resulting from the additives. A proper amount of CuO-MoO3 addition could effectively improve the densification and microwave dielectric properties of ZnO-TiO2 ceramics. ZnO-TiO2 ceramics with 3 wt% addition sintered at 950 °C for 4 h exhibited better microwave dielectric properties as follows: εr of 26.8, a Q×f value of 16780 GHz at 5.42 GHz, and a τ f value of +34.7 ppm/°C.


2009 ◽  
Vol 421-422 ◽  
pp. 69-72
Author(s):  
Jie Shen ◽  
Wen Chen ◽  
Jing Zhou ◽  
Jie Zhu ◽  
Qiong Lei

The relationship between the character of the B-site cation–oxygen bond and the microwave dielectric properties in perovskites dielectric materials was studied in this paper. The atomic net charge of CaTiO3 (CT) and Ca(Zn1/3Nb2/3)O3 (CZN) was calculated respectively. The calculating result implies that the covalency of B-O bonds in CZN is stronger than that in CT. This predicted that the dielectric constant and loss of the ceramics will decrease after CZN incorporated in CT. To confirme the prediction, (1-x)CT-xCZN microwave dielectric ceramics were prepared by solid state reaction method with ZnNb2O6 as precursor. The structure analysis in terms of tolerance factor gives an identical result as calculation. The microwave dielectric properties, such as dielectric constants, Q×f values and τf were studied as a function of composition. With x increasing from 0.2 to 0.8, the dielectric constant linearly decreases from 109 to 49.37, the Q×f value increases from 8,340 to 13,200 GHz, and τf decreases from 321 to -18 ppm/°C. The properties trends are consistent with the previous calculation results, and confirm the relationship between the character of B-O bond and dielectric properties.


2001 ◽  
Vol 16 (3) ◽  
pp. 817-821 ◽  
Author(s):  
Heung Soo Park ◽  
Ki Hyun Yoon ◽  
Eung Soo Kim

The relationship between the dielectric properties of the complex perovskite (Pb1−xCax)(Mg0.33Ta0.67)O3 ceramics, where 0.45 ≤ × ≤ 0.60, and the dielectric polarizability, related to bond valences of A-site ions, was investigated at microwave frequencies. As the Ca content (x) increased, the deviation of the observed dielectric polarizabilities, calculated by the Clausius–Mosotti equation from the theoretical values calculated by the additivity rule of dielectric polarizability, decreased from −3% to −0.69%. It was found that this deviation was related to the bond valence of the A-site. Smaller negative deviation corresponded to the cations with lower bond valence, and larger negative deviation corresponded to the cations with higher bond valence. Also, the temperature coefficient of resonant frequency (TCF) was affected by the bond valence of the A-site, and then TCF decreased with decreasing bond valence of the A-site in ABO3 perovskite compounds.


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