In continuation of earlier experiments (Harrison 1937) in which the thermal diffusion in radon-hydrogen and radon-helium mixtures was measured, the thermal diffusion of mixtures of radon-neon and radon-argon has now been studied. The mean value obtained for the ratio of the proportion by volume of radon on the cold side at 0° C to that on the hot side at 100° C, after thermal diffusion, was 1·074 for radon-neon mixtures, and 1·008 for radon-argon mixtures. In order to calculate the repulsive force field,
F
12
, between these two pairs of molecules, the present results were combined with measurements of ordinary diffiisirm of radon into neon and radon into argon (Hirst & Harrison 1939), and viscosity determinations at various temperatures of neon and argon (Trautz & Binkele 1930). The special theory, due to Chapman (1929), of thermal diffusion of a rare constituent in a binary mixture was used to derive Flt. The values obtained for the repulsive force field between the dissimilar molecules at collision were:
F
12
(radon-neon) = 1·9 x 10
-51
d
-6·1
= (
d
/
d
0
)
-6·1
,
d
0
= 4·8 x 10
-9
,
F
12
(radon-argon) = 2·1 x 10
-43
d
-5·1
= (
d
0
)-5·1
,
d
0
= 4·3 x 10
-9
,
d
being the distance between the point centres of repulsive force and
d
0
the value of
d
at which
F
12
is 1 dyne. A comparison of the values obtained for the repulsive force index for radon-neon and radon-argon molecules with those obtained by Atkins, Bastick & Ibbs (1939) for binary mixtures of the first five inert gases shows that radon is the4 softest ’ of the inert gas molecules. Radon-argon molecules are the closest approach to the Maxwellian case yet studied experimentally.