Photocatalytic electron transfer through the photopassive membrane of lipid vesicles

1983 ◽  
Vol 23 (3-4) ◽  
pp. 409-412 ◽  
Author(s):  
V. N. Parmon ◽  
M. I. Kharmov ◽  
I. M. Tsvetkov ◽  
S. V. Lymar ◽  
K. I. Zamaraev
1984 ◽  
Vol 24 (3-4) ◽  
pp. 395-399 ◽  
Author(s):  
M. I. Kharamov ◽  
S. V. Lymar ◽  
G. B. Maravin ◽  
V. N. Parmon ◽  
K. I. Zamaraev

1994 ◽  
Vol 47 (2) ◽  
pp. 209 ◽  
Author(s):  
M Misran ◽  
D Matthews ◽  
P Valente ◽  
A Hope

Methylene Blue is a well known photochemical oxidant. In this paper we present results of cyclic voltammetry and laser flash photolysis experiments which demonstrate that Methylene Blue may function also as a photochemical reductant. Laser flash photolysis studies of Methylene Blue were carried out in aqueous solution at pH 10, in ethanol and in aqueous dispersions of lipid vesicles in the presence of benzoquinol , benzoquinone and the long-chain naphthoquinone Vitamin K1. Both the quinones and the quinol affected the transient of the decay of triplet Methylene Blue to its ground electronic state. The transients were biphasic and characteristic of an initial electron transfer reaction between triplet Methylene Blue and the quinone or quinol , followed by back electron transfer between the products. For Vitamin K1 and Methylene Blue in ethanol the back electron transfer was very slow (lifetime about 4 ms). This slow back electron transfer is favourable to the use of this system for energy storage via photosynthetic solar energy conversion.


Author(s):  
P. Bonhomme ◽  
A. Beorchia

We have already described (1.2.3) a device using a pockel's effect light valve as a microscopical electron image converter. This converter can be read out with incoherent or coherent light. In the last case we can set in line with the converter an optical diffractometer. Now, electron microscopy developments have pointed out different advantages of diffractometry. Indeed diffractogram of an image of a thin amorphous part of a specimen gives information about electron transfer function and a single look at a diffractogram informs on focus, drift, residual astigmatism, and after standardizing, on periods resolved (4.5.6). These informations are obvious from diffractogram but are usualy obtained from a micrograph, so that a correction of electron microscope parameters cannot be realized before recording the micrograph. Diffractometer allows also processing of images by setting spatial filters in diffractogram plane (7) or by reconstruction of Fraunhofer image (8). Using Electrotitus read out with coherent light and fitted to a diffractometer; all these possibilities may be realized in pseudoreal time, so that working parameters may be optimally adjusted before recording a micrograph or before processing an image.


Author(s):  
Uwe Lücken ◽  
Joachim Jäger

TEM imaging of frozen-hydrated lipid vesicles has been done by several groups Thermotrophic and lyotrophic polymorphism has been reported. By using image processing, computer simulation and tilt experiments, we tried to learn about the influence of freezing-stress and defocus artifacts on the lipid polymorphism and fine structure of the bilayer profile. We show integrated membrane proteins do modulate the bilayer structure and the morphology of the vesicles.Phase transitions of DMPC vesicles were visualized after freezing under equilibrium conditions at different temperatures in a controlled-environment vitrification system. Below the main phase transition temperature of 24°C (Fig. 1), vesicles show a facetted appearance due to the quasicrystalline areas. A gradual increase in temperature leads to melting processes with different morphology in the bilayer profile. Far above the phase transition temperature the bilayer profile is still present. In the band-pass-filtered images (Fig. 2) no significant change in the width of the bilayer profile is visible.


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