One-step synthesis of triarm block copolymers by simultaneous atom transfer radical and ring-opening polymerization

2015 ◽  
Vol 73 (6) ◽  
pp. 1497-1513 ◽  
Author(s):  
Temel Öztürk ◽  
Mahmut Yavuz ◽  
Melahat Göktaş ◽  
Baki Hazer
Keyword(s):  
Block Copolymers ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
One Step

Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

2017 ◽  
Vol 8 (19) ◽  
pp. 2899-2903 ◽  
Author(s):  
Cansu Aydogan ◽  
Ceren Kutahya ◽  
Andrit Allushi ◽  
Gorkem Yilmaz ◽  
Yusuf Yagci
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Metal Free

A completely metal-free strategy was developed by combining Atom Transfer Radical Polymerization (ATRP) and Ring Opening Polymerization (ROP) for the syntheses of block copolymers.

One-step synthesis of poly(methacrylate)-b-polyester via “one organocatalyst, two polymerizations”

2021 ◽  
Author(s):  
Mengmeng Li ◽  
Lin Zhou ◽  
Ziqi Zhang ◽  
Qi Wang ◽  
Jiani Gao ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Methyl Methacrylate ◽  
Ambient Temperature ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Trimethylene Carbonate ◽  
One Step

By using triarylsulfonium hexafluorophosphate salt as an organocatalyst for both photo-controlled atom transfer radical polymerization (photo-ATRP) and ring-opening polymerization (ROP) at ambient temperature, well-defined poly(methyl methacrylate)-b-poly(trimethylene carbonate) block copolymer was...

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